Principles Of Adsorption And Reaction On Solid Surfaces

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Principles of Adsorption and Reaction on Solid Surfaces

Author : Richard I. Masel
Publisher : John Wiley & Sons
Page : 826 pages
File Size : 55,5 Mb
Release : 1996-03-22
Category : Technology & Engineering
ISBN : 0471303925

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Principles of Adsorption and Reaction on Solid Surfaces by Richard I. Masel Pdf

Principles of Adsorption and Reaction on Solid Surfaces As with other books in the field, Principles of Adsorption and Reaction on Solid Surfaces describes what occurs when gases come in contact with various solid surfaces. But, unlike all the others, it also explains why. While the theory of surface reactions is still under active development, the approach Dr. Richard Masel takes in this book is to outline general principles derived from thermodynamics and reaction rate theory that can be applied to reactions on surfaces, and to indicate ways in which these principles may be applied. The book also provides a comprehensive treatment of the latest quantitative surface modeling techniques with numerous examples of their use in the fields of chemical engineering, physical chemistry, and materials science. A valuable working resource and an excellent graduate-level text, Principles of Adsorption and Reaction on Solid Surfaces provides readers with: * A detailed look at the latest advances in understanding and quantifying reactions on surfaces * In-depth reviews of all crucial background material * 40 solved examples illustrating how the methods apply to catalysis, physical vapor deposition, chemical vapor deposition, electrochemistry, and more * 340 problems and practice exercises * Sample computer programs * Universal plots of many key quantities * Detailed, class-tested derivations to help clarify key results The recent development of quantitative techniques for modeling surface reactions has led to a number of exciting breakthroughs in our understanding of what happens when gases come in contact with solid surfaces. While many books have appeared describing various experimental modeling techniques and the results obtained through their application, until now, there has been no single-volume reference devoted to the fundamental principles governing the processes observed. The first book to focus on governing principles rather than experimental techniques or specific results, Principles of Adsorption and Reaction on Solid Surfaces provides students and professionals with a quantitative treatment of the application of principles derived from the fields of thermodynamics and reaction rate theory to the investigation of gas adsorption and reaction on solid surfaces. Writing for a broad-based audience including, among others, chemical engineers, chemists, and materials scientists, Dr. Richard I. Masel deftly balances basic background in areas such as statistical mechanics and kinetics with more advanced applications in specialized areas. Principles of Adsorption and Reaction on Solid Surfaces was also designed to provide readers an opportunity to quickly familiarize themselves with all of the important quantitative surface modeling techniques now in use. To that end, the author has included all of the key equations involved as well as numerous real-world illustrations and solved examples that help to illustrate how the equations can be applied. He has also provided computer programs along with universal plots that make it easy for readers to apply results to their own problems with little computational effort. Principles of Adsorption and Reaction on Solid Surfaces is a valuable working resource for chemical engineers, physical chemists, and materials scientists, and an excellent text for graduate students in those disciplines.

Reactions at Solid Surfaces

Author : Gerhard Ertl
Publisher : John Wiley & Sons
Page : 150 pages
File Size : 55,9 Mb
Release : 2010-06-17
Category : Science
ISBN : 0470535288

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Reactions at Solid Surfaces by Gerhard Ertl Pdf

Expanding on the ideas first presented in Gerhard Ertl's acclaimed Baker Lectures at Cornell University, Reactions at Solid Surfaces comprises an authoritative, self-contained, book-length introduction to surface reactions for both professional chemists and students alike. Outlining our present understanding of the fundamental processes underlying reactions at solid surfaces, the book provides the reader with a complete view of how chemistry works at surfaces, and how to understand and probe the dynamics of surface reactions. Comparing traditional surface probes with more modern ones, and bringing together various disciplines in a cohesive manner, Gerhard Ertl's Reactions at Solid Surfaces serves well as a primary text for graduate students in introductory surface science or chemistry, as well as a self-teaching resource for professionals in surface science, chemical engineering, or nanoscience.

Films on Solid Surfaces

Author : J.G. Dash
Publisher : Elsevier
Page : 286 pages
File Size : 53,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323157612

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Films on Solid Surfaces by J.G. Dash Pdf

Films on Solid Surfaces presents the physics and chemistry of physical adsorption. This book contains 10 chapters that are ordered according to the flow of a course given in a graduate study in University of Washington during 1973. The introductory chapter presents the motivation for the completion of the book. As the motivating factors are established, the book follows with the topic on atomic nature of physical adsorption and the states of single adsorbed atoms. A review of experimental techniques for the study of solid surfaces and films is given, as well as a discussion of substrate preparation and equilibrium thermodynamics. The various states of films and their phase transitions encompass four chapters. Lastly, the book also reviews thin film superfluidity. This book specifically caters to scientists in the fields of physics and biology working on physical adsorption and surface science.

Principles of Surface Chemistry

Author : Gabor A. Somorjai
Publisher : Unknown
Page : 314 pages
File Size : 51,5 Mb
Release : 1972
Category : Surface chemistry
ISBN : UCAL:B3728846

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Principles of Surface Chemistry by Gabor A. Somorjai Pdf

Principles of Adsorption and Adsorption Processes

Author : Douglas M. Ruthven
Publisher : John Wiley & Sons
Page : 466 pages
File Size : 43,7 Mb
Release : 1984-06-05
Category : Technology & Engineering
ISBN : 0471866067

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Principles of Adsorption and Adsorption Processes by Douglas M. Ruthven Pdf

The first up-to-date summary and review for the fundamental principles and industrial practice of adsorption separation processes in more than 30 years. Emphasizes the understanding of adsorption column dynamics and the modeling of adsorption systems, as well as fundamental aspects of kinetics and equilibria.

Exoemission from Processed Solid Surfaces and Gas Adsorption

Author : Yoshihiro Momose
Publisher : Springer Nature
Page : 238 pages
File Size : 42,6 Mb
Release : 2022-11-24
Category : Technology & Engineering
ISBN : 9789811969485

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Exoemission from Processed Solid Surfaces and Gas Adsorption by Yoshihiro Momose Pdf

This book focuses on surface activity of electron emission (EE). Prior to protective painting, a steel surface is usually grit blasted or sandblasted to remove scale and contaminants and to roughen the surface. This book emphasizes that such surface treatment causes EE, increasing the strength of paint adhesion. Introduced here are the experimental results of thermally assisted photoelectron emission (TAPE) and tribo-stimulated (rubbing) electron emission (TriboEE) from practical metals after different kinds of surface-treatment processes. A detailed description is given of how Arrhenius activation energies relating to electron transfer through the surface overlayer and also the energy levels of electrons trapped in the overlayer can be obtained, and how TAPE and TriboEE data can be influenced by the chemical properties of that overlayer. This book is composed of four parts: I. Surface treatment processes; II. The principle of EE analysis used for practical surfaces; III. Materials and methods of EE and X-ray photoelectron spectroscopy (XPS); IV. EE and XPS characteristics of practical surfaces. In the last part, the EE and XPS results for metals, semiconductors, and carbon materials are drawn from the author’s own publications. The book will be useful for researchers engaging in surface-treatment processes of various materials.

Inorganic Chemistry

Author : James E. House
Publisher : Academic Press
Page : 978 pages
File Size : 50,5 Mb
Release : 2019-11-01
Category : Science
ISBN : 9780128143704

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Inorganic Chemistry by James E. House Pdf

Inorganic Chemistry, Third Edition, emphasizes fundamental principles, including molecular structure, acid-base chemistry, coordination chemistry, ligand field theory and solid state chemistry. The book is organized into five major themes: structure, condensed phases, solution chemistry, main group and coordination compounds, each of which is explored with a balance of topics in theoretical and descriptive chemistry. Topics covered include the hard-soft interaction principle to explain hydrogen bond strengths, the strengths of acids and bases, and the stability of coordination compounds, etc. Each chapter opens with narrative introductions and includes figures, tables and end-of-chapter problem sets. This new edition features updates throughout, with an emphasis on bioinorganic chemistry and a new chapter on nanostructures and graphene. In addition, more in-text worked-out examples encourage active learning and prepare students for exams. This text is ideal for advanced undergraduate and graduate-level students enrolled in the Inorganic Chemistry course. Includes physical chemistry to show the relevant principles from bonding theory and thermodynamics Emphasizes the chemical characteristics of main group elements and coordination chemistry Presents chapters that open with narrative introductions, figures, tables and end-of-chapter problem sets

Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Author : W.A. Steele,G. Zgrablich,W. Rudzinski
Publisher : Elsevier
Page : 883 pages
File Size : 53,8 Mb
Release : 1996-12-17
Category : Technology & Engineering
ISBN : 0080531199

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Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces by W.A. Steele,G. Zgrablich,W. Rudzinski Pdf

The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems. Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.

Handbook of Materials Modeling

Author : Sidney Yip
Publisher : Springer Science & Business Media
Page : 2903 pages
File Size : 44,5 Mb
Release : 2007-11-17
Category : Science
ISBN : 9781402032868

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Handbook of Materials Modeling by Sidney Yip Pdf

The first reference of its kind in the rapidly emerging field of computational approachs to materials research, this is a compendium of perspective-providing and topical articles written to inform students and non-specialists of the current status and capabilities of modelling and simulation. From the standpoint of methodology, the development follows a multiscale approach with emphasis on electronic-structure, atomistic, and mesoscale methods, as well as mathematical analysis and rate processes. Basic models are treated across traditional disciplines, not only in the discussion of methods but also in chapters on crystal defects, microstructure, fluids, polymers and soft matter. Written by authors who are actively participating in the current development, this collection of 150 articles has the breadth and depth to be a major contributor toward defining the field of computational materials. In addition, there are 40 commentaries by highly respected researchers, presenting various views that should interest the future generations of the community. Subject Editors: Martin Bazant, MIT; Bruce Boghosian, Tufts University; Richard Catlow, Royal Institution; Long-Qing Chen, Pennsylvania State University; William Curtin, Brown University; Tomas Diaz de la Rubia, Lawrence Livermore National Laboratory; Nicolas Hadjiconstantinou, MIT; Mark F. Horstemeyer, Mississippi State University; Efthimios Kaxiras, Harvard University; L. Mahadevan, Harvard University; Dimitrios Maroudas, University of Massachusetts; Nicola Marzari, MIT; Horia Metiu, University of California Santa Barbara; Gregory C. Rutledge, MIT; David J. Srolovitz, Princeton University; Bernhardt L. Trout, MIT; Dieter Wolf, Argonne National Laboratory.

Chemistry and Physics of Solid Surfaces VII

Author : Ralf Vanselow,Russell F. Howe
Publisher : Springer Science & Business Media
Page : 626 pages
File Size : 47,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642739026

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Chemistry and Physics of Solid Surfaces VII by Ralf Vanselow,Russell F. Howe Pdf

This volume contains review articles written by the invited speakers at the eighth International Summer Institute in Surface Science (ISISS 1987), held at the University of Wisconsin-Milwaukee in August of 1987. During the course of ISISS, invited speakers, all internationally recognized experts in the various fields of surface science, present tutorial review lectures. In addition, these experts are asked to write review articles on their lecture topic. Former ISISS speakers serve as advisors concerning the selection of speakers and lecture topics. Em phasis is given to those areas which have not been covered in depth by recent Summer Institutes, as well as to areas which have recently gained in significance and in which important progress has been made. Because of space limitations, no individual volume of Chemistry and Physics of Solid Surfaces can possibly cover the whole area of modem surface science, or even give a complete survey of recent pro gress in the field. However, an attempt is made to present a balanced overview in the series as a whole. With its comprehensive literature references and extensive subject indices, this series has become a valu able resource for experts and students alike. The collected articles, which stress particularly the gas-solid interface, have been published under the following titles: Surface Science: Recent Progress and Perspectives, Crit. Rev. Solid State Sci. 4, 125-559 (1974) Chemistry and Physics of Solid Surfaces, Vols. I, II, and III (CRC Press Boca Raton, FL 1976, 1979, and 1982); Vols.

Solid Surfaces, Interfaces and Thin Films

Author : Hans Lüth
Publisher : Springer Science & Business Media
Page : 559 pages
File Size : 51,7 Mb
Release : 2013-04-17
Category : Technology & Engineering
ISBN : 9783662043523

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Solid Surfaces, Interfaces and Thin Films by Hans Lüth Pdf

This book emphasises both experimental and theoretical aspects of surface, interface and thin film physics. Compa- red to the earlier editions, which bore the title "Surfaces and Interfaces of Solid Materials", the book now places more emphasis on thin films, including also their superconducting and ferromagnetic properties. The present 4th edition thus presents techniques of preparing well-defined solid surfaces and interfaces, fundamental aspects of adsorption and layer growth, as well as basic models for the descripti- on of structural, vibronic and electronic properties of sur- faces, interfaces and thin films. Because of their importan- ce for modern information technology, significant attention is paid to the electronic properties of semiconductor inter- faces and heterostructures. Collective phenomena , such as superconductivity and ferromagnetism, also feature promi- nently. Experimental sections covering essential measurement and preparation techniques are presented in separate panels.

Adsorption by Powders and Porous Solids

Author : Jean Rouquerol,Françoise Rouquerol,Philip Llewellyn,Guillaume Maurin,Kenneth S.W. Sing
Publisher : Academic Press
Page : 646 pages
File Size : 41,7 Mb
Release : 2013-09-06
Category : Science
ISBN : 9780080970363

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Adsorption by Powders and Porous Solids by Jean Rouquerol,Françoise Rouquerol,Philip Llewellyn,Guillaume Maurin,Kenneth S.W. Sing Pdf

The declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeolites. Provides a comprehensive treatment of adsorption at both the gas/solid interface and the liquid/solid interface Includes chapters dealing with experimental methodology and the interpretation of adsorption data obtained with porous oxides, carbons and zeolites Techniques capture the importance of heterogeneous catalysis, chemical engineering and the production of pigments, cements, agrochemicals, and pharmaceuticals

Multiphase Catalytic Reactors

Author : Zeynep Ilsen Önsan,Ahmet Kerim Avci
Publisher : John Wiley & Sons
Page : 395 pages
File Size : 53,6 Mb
Release : 2016-07-05
Category : Technology & Engineering
ISBN : 9781118115763

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Multiphase Catalytic Reactors by Zeynep Ilsen Önsan,Ahmet Kerim Avci Pdf

Provides a holistic approach to multiphase catalytic reactors from their modeling and design to their applications in industrial manufacturing of chemicals Covers theoretical aspects and examples of fixed-bed, fluidized-bed, trickle-bed, slurry, monolith and microchannel reactors Includes chapters covering experimental techniques and practical guidelines for lab-scale testing of multiphase reactors Includes mathematical content focused on design equations and empirical relationships characterizing different multiphase reactor types together with an assortment of computational tools Involves detailed coverage of multiphase reactor applications such as Fischer-Tropsch synthesis, fuel processing for fuel cells, hydrotreating of oil fractions and biofuels processing

The Chemical Physics of Solid Surfaces

Author : D.A. King
Publisher : Elsevier
Page : 362 pages
File Size : 46,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444601551

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The Chemical Physics of Solid Surfaces by D.A. King Pdf

The Chemical Physics of Solid Surfaces, Volume 6: Coadsorption, Promoters, and Poisons focuses on the processes, reactions, and approaches involved in coadsorption and the functions of promoters and poisons in synthesis and reactions. The selection first offers information on adsorbate-adsorbate interactions on metal surfaces and interaction between alkali metal adsorbates and adsorbed molecules. Discussions focus on coadsorption of alkali metals and other molecules; model experiments of catalyst promotion; effective medium theory; direct and indirect hybridization effects; and elastic interaction between adsorbates. The publication then ponders on coadsorption of carbon monoxide and hydrogen on metal surfaces and adsorption on bimetallic surfaces. The manuscript examines the chemical properties of alloy single crystal surfaces and promotion in ammonia synthesis. Topics include substrate dependence of nitrogen adsorption and ammonia synthesis; effects of promotion on nitrogen dissociation and ammonia synthesis; and theoretical modeling. The text then elaborates on promotion in the Fischer-Tropsch hydrocarbon synthesis, promoters and poisons in the water-gas shift reaction, and strong metal-support interactions. The selection is a recommended reference for physicists and readers interested in coadsorption, promoters, and poisons.