Solid Acid Catalysis

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Solid Acid Catalysis

Author : Hideshi Hattori,Yoshi Ono
Publisher : CRC Press
Page : 530 pages
File Size : 49,6 Mb
Release : 2015-04-01
Category : Science
ISBN : 9789814463294

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Solid Acid Catalysis by Hideshi Hattori,Yoshi Ono Pdf

Solids that possess acidic properties on their surfaces function as catalysts just like liquid acids, such as sulfuric acid and hydrochloric acid. By using solid acid catalysts, chemical processes become more productive and more environmentally friendly. In fact, solid acids are being used in many industrial chemical processes from the largest chemical process of catalytic cracking in petroleum refining to the synthesis of various fine chemicals. This book covers the fundamentals of solid acid catalysis, including its history and characterization, and discusses different types of catalysts and solid acid-catalyzed reactions as well as their industrial applications. It comprehensively covers from fundamentals to applications and will be useful for students, young researchers, and advanced researchers.

Solid Acid Catalysis

Author : Hideshi Hattori,Yoshi Ono
Publisher : Unknown
Page : 530 pages
File Size : 49,9 Mb
Release : 2015
Category : Electronic
ISBN : OCLC:1192535239

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Solid Acid Catalysis by Hideshi Hattori,Yoshi Ono Pdf

Solids that possess acidic properties on their surfaces function as catalysts just like liquid acids, such as sulfuric acid and hydrochloric acid. By using solid acid catalysts, chemical processes become more productive and more environmentally friendly. In fact, solid acids are being used in many industrial chemical processes from the largest chemical process of catalytic cracking in petroleum refining to the synthesis of various fine chemicals. This book covers the fundamentals of solid acid catalysis, including its history and characterization, and discusses different types of catalysts and solid acid-catalyzed reactions as well as their industrial applications. It comprehensively covers from fundamentals to applications and will be useful for students, young researchers, and advanced researchers.

Solid Acids and Bases

Author : Kozo Tanabe
Publisher : Elsevier
Page : 184 pages
File Size : 43,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323160582

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Solid Acids and Bases by Kozo Tanabe Pdf

Solid Acids and Bases: Their Catalytic Properties reviews developments in the studies of acidic and basic properties of solids, including the efficacy and special characteristics of solid acid and base catalysts. This book discusses the determination of basic and acidic properties on solid surfaces and relationship between acid strength and acid amount. The structure and acid-base properties of mixed metal oxides and correlation between acid-base properties and catalytic activity and selectivity are also deliberated. This publication is useful to professional chemists and graduate students in the fields of organic, inorganic and physical chemistry, petroleum chemistry and catalysis, including readers interested in the acidic and basic properties on solid surfaces.

New Solid Acids and Bases

Author : K. Tanabe,M. Misono,H. Hattori,Y. Ono
Publisher : Elsevier
Page : 364 pages
File Size : 50,6 Mb
Release : 1990-02-02
Category : Technology & Engineering
ISBN : 0080887554

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New Solid Acids and Bases by K. Tanabe,M. Misono,H. Hattori,Y. Ono Pdf

This volume summarises and reviews the enormous progress made over the past two decades in solid acids and bases, with emphasis on fundamental aspects and chemical principles. In recent years many new kinds of solid acids and bases have been found and synthesized. The surface properties (in particular, acidic and basic properties) and the structures of the new solids have been clarified by newly developed measurement methods using modern instruments and techniques. The characterized solid acids and bases have been applied as catalysts for diversified reactions, many good correlations being obtained between the acid-base properties and the catalytic activities or selectivities. Recently, acid-base bifunctional catalysis on solid surfaces is becoming a more and more important and intriguing field of study. It has been recognized that the acidic and basic properties of catalysts and catalyst supports play an important role in oxidation, reduction, hydrogenation, hydrocracking, etc. The effect of the preparation method and the pretreatment conditions of solid acids and bases on the acidic and basic properties, the nature of acidic and basic sites and the mechanism regarding the generation of acidity and basicity have been elucidated experimentally and theoretically. On the basis of the accumulated knowledge of solid acids and bases, it is now possible to design and develop highly active and selective solid acid and base catalysts for particular reactions. The chemistry of solid acids and bases is now being related to and utilized in numerous areas including adsorbents, sensors, cosmetics, fuel cells, sensitized pressed papers, and others. The information presented in this book will therefore be of interest to a wide-ranging readership.

Solid Base Catalysis

Author : Yoshio Ono,Hideshi Hattori
Publisher : Springer Science & Business Media
Page : 431 pages
File Size : 40,7 Mb
Release : 2012-08-31
Category : Science
ISBN : 9783642183393

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Solid Base Catalysis by Yoshio Ono,Hideshi Hattori Pdf

The importance of solid base catalysts has come to be recognized for their environmentally benign qualities, and much significant progress has been made over the past two decades in catalytic materials and solid base-catalyzed reactions. The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding. Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are less difficult, and they are non-corrosive. Furthermore, base-catalyzed reactions can be performed without using solvents and even in the gas phase, opening up more possibilities for discovering novel reaction systems. Using numerous examples, the present volume describes the remarkable role solid base catalysis can play, given the ever increasing worldwide importance of "green" chemistry. The reader will obtain an overall view of solid base catalysis and gain insight into the versatility of the reactions to which solid base catalysts can be utilized. The concept and significance of solid base catalysis are discussed, followed by descriptions of various methods for the characterization of solid bases, including spectroscopic methods and test reactions. The preparation and properties of base materials are presented in detail, with the two final chapters devoted to surveying the variety of reactions catalyzed by solid bases.

Catalysis by Acids and Bases

Author : B. Imelik,C. Naccache,G. Coudurier,Y. Ben Taarit,J.C. Vedrine
Publisher : Elsevier
Page : 444 pages
File Size : 47,7 Mb
Release : 1985-02-01
Category : Technology & Engineering
ISBN : 0080960545

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Catalysis by Acids and Bases by B. Imelik,C. Naccache,G. Coudurier,Y. Ben Taarit,J.C. Vedrine Pdf

Because of the great importance of acid catalysis in the petrochemical industry, extensive research has been carried out during the last 30 years concerning the fundamental and applied aspects of catalysis by acids. In contrast, base-catalyzed reactions have received little attention in heterogeneous catalysis. The aim of this symposium was to evaluate our knowledge of the important area of acid and base catalysis and to cover a broad range of solids, zeolite chemistry being only one aspect of heterogeneous catalysis.

Fine Chemicals through Heterogeneous Catalysis

Author : R. A. Sheldon,Herman van Bekkum
Publisher : John Wiley & Sons
Page : 636 pages
File Size : 53,6 Mb
Release : 2008-07-11
Category : Science
ISBN : 9783527612970

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Fine Chemicals through Heterogeneous Catalysis by R. A. Sheldon,Herman van Bekkum Pdf

Nowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production. With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.

Characterization and Design of Zeolite Catalysts

Author : Miki Niwa,Naonobu Katada,Kazu Okumura
Publisher : Springer Science & Business Media
Page : 189 pages
File Size : 44,5 Mb
Release : 2010-08-17
Category : Science
ISBN : 9783642126208

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Characterization and Design of Zeolite Catalysts by Miki Niwa,Naonobu Katada,Kazu Okumura Pdf

Catalysis and catalyst is a key technology to solve the problems in energy and environment issues to sustain our human society. We believe that comprehensive understanding of the catalysis and catalyst provides us a chance to develop a new catalyst and contributes greatly to our society. However, the ?eld of heterogeneous catalyst is dif?cultto study andstill stays behindmoredeveloped?elds ofchemistry such as organic and physical chemistries. This is a dilemma to the chemists who study the catalysis and catalyst. While we can accomplish the progress in the - dustrial application, the scienti?c understandingis not complete yet. A gap between the useful application and incomplete scienti?c understanding, however, becomes smaller and smaller in recent years. Because zeolites are ?ne crystals, and the structure is clearly known, the study on the catalysis using the zeolites is easier than those encountered in other catalysts such as metals and metal oxides. Very fortunately, zeolites provide us the strong acidity with the ?ne distribution which enables various useful catalytic reactions. When some metals and cations are loaded in close to the acid sites, these loadede- ments show extraordinarycharacters, and many catalytic reactions proceed thereon.

Solid Superacids

Author : Kazushi Arata,Hiromi Matsuhashi
Publisher : Unknown
Page : 0 pages
File Size : 46,7 Mb
Release : 2011
Category : Superacids
ISBN : 1612096492

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Solid Superacids by Kazushi Arata,Hiromi Matsuhashi Pdf

An acid that is stronger than the acid strength of 100% sulphuric acid is known as a superacid. Environmental concerns about the use of toxic liquid superacids and liquid inorganic acids in the transformation of hydrocarbons provide an impetus for a search of stable and more environmentally friendly solid acid catalysts. This book examines an important opportunity related to green chemistry where solid superacids lead to new gas- and liquid-solid phase reactions, which are environmentally benign processes in the chemical industry.

Acid-Base Catalysis II

Author : H. Hattori,M. Misono,Y. Ono
Publisher : Elsevier
Page : 556 pages
File Size : 42,7 Mb
Release : 1994-11-01
Category : Technology & Engineering
ISBN : 008088752X

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Acid-Base Catalysis II by H. Hattori,M. Misono,Y. Ono Pdf

Solid acid catalysts are already being used in various processes in petroleum refining and are presently being studied intensively in both academic and applied fields for usage in a variety of reactions. Solid base catalysts are also gaining increasing recognition as potential catalysts. Both acidic and basic catalysts are promising not only with respect to acid and base-catalyzed reactions but also in materials sciences, such as the production of adsorbents, sensors, ceramics, etc. The present volume presents the text of 21 invited oral presentations and 58 poster presentations. The material covers a wide range of aspects on acid-base catalysis, from quantum chemistry to industrialized processes.

Advances in Catalysis

Author : Anonim
Publisher : Academic Press
Page : 144 pages
File Size : 44,9 Mb
Release : 2020-11-25
Category : Science
ISBN : 9780128203750

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Advances in Catalysis by Anonim Pdf

Advances in Catalysis, Volume 67, fills the gap between journal papers and textbooks across the diverse areas of catalysis research. For more than 60 years, this series has dedicated itself to record and present the latest progress in the field of catalysis, providing the scientific community with comprehensive and authoritative reviews. This series is an invaluable and comprehensive resource for chemical engineers and chemists working in the field of catalysis in both academia and industry, with this release focusing on solid acids, surface acidity and heterogeneous acid catalysis. Contains authoritative reviews written by experts in the field Explores topics that reflect progress in the field, such as catalyst synthesis, catalyst characterization, catalytic chemistry, reaction engineering, computational chemistry and physics Provides insightful and critical articles that are fully edited to suit various backgrounds

Preparation of Solid Catalysts

Author : Gerhard Ertl,Helmut Knözinger,Jens Weitkamp
Publisher : John Wiley & Sons
Page : 639 pages
File Size : 40,7 Mb
Release : 2008-08-29
Category : Science
ISBN : 9783527620685

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Preparation of Solid Catalysts by Gerhard Ertl,Helmut Knözinger,Jens Weitkamp Pdf

Solid catalysts play a fundamental role in all areas between basic research and industrial applications. This book offers a large amount of information about the preparation of solid catalysts. All types of solid catalysts and all important aspects of their preparation are discussed. The highly topical contributions are written by leading experts in disciplines ranging from solid state, interface and solution chemistry to industrial engineering. The straightforward presentation of the material and the comprehensive coverage make this book an essential and indispensible tool for every scientist and engineer working with solid catalysts.

Keynotes in Energy-Related Catalysis

Author : S. Kaliaguine
Publisher : Elsevier
Page : 451 pages
File Size : 49,5 Mb
Release : 2011-09-22
Category : Technology & Engineering
ISBN : 9780080960692

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Keynotes in Energy-Related Catalysis by S. Kaliaguine Pdf

Catalysis by solid acids, which includes (modified) zeolites, is of special relevance to energy applications. Acid catalysis is highly important in modern petroleum refining operations - large-scale processes such as fluid catalytic cracking, catalytic reforming, alkylation and olefin oligomerization rely on the transformation of hydrocarbons by acid catalysts. (Modified) zeolites are therefore essential for the improvement of existing processes and for technical innovations in the conversion of crude. There can be little doubt that zeolite-based catalysts will play a major role in the future management of fossil fuels and biomass, and this book is intended to contribute to tomorrow's achievements in this area.Each chapter presents the personal views of an expert, or a small group of experts, on the current state of the art, and on the trends in his/their field likely to lead to important developments. The presentation of these various keynotes in one volume will provide inspiration to the reader interested in the development of zeolite-based catalysts for energy applications, and in particular will suggest to the new-comer in the field of catalyst design, methods to develop his own original orientations.

Bridging Heterogeneous and Homogeneous Catalysis

Author : Can Li,Yan Liu
Publisher : John Wiley & Sons
Page : 860 pages
File Size : 46,7 Mb
Release : 2014-04-03
Category : Technology & Engineering
ISBN : 9783527675920

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Bridging Heterogeneous and Homogeneous Catalysis by Can Li,Yan Liu Pdf

There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions. This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis. Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations. With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.

Characterization of Solid Materials and Heterogeneous Catalysts

Author : Michel Che,Jacques C. Vedrine
Publisher : John Wiley & Sons
Page : 1313 pages
File Size : 45,8 Mb
Release : 2012-04-16
Category : Technology & Engineering
ISBN : 9783527645336

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Characterization of Solid Materials and Heterogeneous Catalysts by Michel Che,Jacques C. Vedrine Pdf

This two-volume book provides an overview of physical techniques used to characterize the structure of solid materials, on the one hand, and to investigate the reactivity of their surface, on the other. Therefore this book is a must-have for anyone working in fields related to surface reactivity. Among the latter, and because of its most important industrial impact, catalysis has been used as the directing thread of the book. After the preface and a general introduction to physical techniques by M. Che and J.C. Vedrine, two overviews on physical techniques are presented by G. Ertl and Sir J.M. Thomas for investigating model catalysts and porous catalysts, respectively. The book is organized into four parts: Molecular/Local Spectroscopies, Macroscopic Techniques, Characterization of the Fluid Phase (Gas and/ or Liquid), and Advanced Characterization. Each chapter focuses upon the following important themes: overview of the technique, most important parameters to interpret the experimental data, practical details, applications of the technique, particularly during chemical processes, with its advantages and disadvantages, conclusions.