Structure And Motion In Polymer Glasses

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Structure and Motion in Polymer Glasses

Author : Anonim
Publisher : Unknown
Page : 278 pages
File Size : 48,6 Mb
Release : 1980
Category : Glass-reinforced plastics
ISBN : UOM:39015049074076

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Structure and Motion in Polymer Glasses by Anonim Pdf

Structure and motion in polymer glasses

Author : Europhysics Conference on Macromolecular Physics (10, 1980, Noordwijkerhout)
Publisher : Unknown
Page : 230 pages
File Size : 55,7 Mb
Release : 1980
Category : Electronic
ISBN : OCLC:634779908

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Structure and motion in polymer glasses by Europhysics Conference on Macromolecular Physics (10, 1980, Noordwijkerhout) Pdf

Molecular Mobility in Deforming Polymer Glasses

Author : Nikhil Padhye
Publisher : Springer Nature
Page : 111 pages
File Size : 55,8 Mb
Release : 2021-10-15
Category : Science
ISBN : 9783030825591

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Molecular Mobility in Deforming Polymer Glasses by Nikhil Padhye Pdf

This book bridges disparate fields in an exploration of the phenomena and applications surrounding molecular mobility in glassy materials experiencing inelastic deformation. The subjects of plastic deformation and polymer motion/interdiffusion currently belong to the two different fields of continuum mechanics and polymer physics, respectively. However, molecular motion associated with plastic deformation is a key ingredient to gain fundamental understanding, both at the macroscopic and microscopic level. This short monograph provides necessary background in the aforementioned fields before addressing the topic of molecular mobility accompanied by macroscopic inelastic deformation in an accessible and easy-to-understand manner. A new phenomenon of solid-state deformation-induced bonding in polymers is discussed in detail, along with some broad implications in several manufacturing sectors. Open questions pertaining to mechanisms, mechanics, and modeling of deformation-induced bonding in polymers are presented. The book’s clear language and careful explanations will speak to readers of diverse backgrounds.

The Physics of Glassy Polymers

Author : R. N. Haward
Publisher : Springer Science & Business Media
Page : 635 pages
File Size : 52,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401023559

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The Physics of Glassy Polymers by R. N. Haward Pdf

This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.

Structure and Properties of Glassy Polymers

Author : Martin R. Tant,Anita J. Hill
Publisher : Unknown
Page : 486 pages
File Size : 45,6 Mb
Release : 1998
Category : Amorphous substances
ISBN : UOM:39015042820830

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Structure and Properties of Glassy Polymers by Martin R. Tant,Anita J. Hill Pdf

In twenty-nine chapters by leading authorities, Structure and Properties of Glassy Polymers provides readers with comprehensive coverage of basic and applied research on glass polymers as well as a wealth of information on current topics such as molecular modeling, characterization, polymer glasses in confined spaces, and conducting glass polymers. The characterization techniques presented include temperature-modulated differential scanning calorimetry, dielectric loss spectroscopy, photochemical hole burning, positron annihilation lifetime spectroscopy, and transient current generation.

Polymer Physics

Author : Leszek A. Utracki,Alexander M. Jamieson
Publisher : John Wiley & Sons
Page : 677 pages
File Size : 46,5 Mb
Release : 2011-02-14
Category : Technology & Engineering
ISBN : 9781118062951

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Polymer Physics by Leszek A. Utracki,Alexander M. Jamieson Pdf

Providing a comprehensive review of the state-of-the-art advanced research in the field, Polymer Physics explores the interrelationships among polymer structure, morphology, and physical and mechanical behavior. Featuring contributions from renowned experts, the book covers the basics of important areas in polymer physics while projecting into the future, making it a valuable resource for students and chemists, chemical engineers, materials scientists, and polymer scientists as well as professionals in related industries.

Polymer Glasses

Author : Connie B. Roth
Publisher : CRC Press
Page : 573 pages
File Size : 50,5 Mb
Release : 2016-12-12
Category : Science
ISBN : 9781315305141

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Polymer Glasses by Connie B. Roth Pdf

"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers

Author : L. Volynskii,N. F. Bakeev
Publisher : CRC Press
Page : 509 pages
File Size : 51,5 Mb
Release : 2018-09-03
Category : Science
ISBN : 9781315359946

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Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers by L. Volynskii,N. F. Bakeev Pdf

Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers explores the role of various surface phenomena in the structural and mechanical behaviour of amorphous and semicrystalline polymers. This book: Discusses the development of the interfacial surface in the deformation of polymers Examines the healing of interfacial surfaces in polymers Inspects the structure and properties of polymers in thin films and surface layers Evaluates the mechanism of inelastic deformation in glassy amorphous polymers Investigates strain softening and the phenomena taking place upon deformation of polymers in active liquid media Covers the Rehbinder effect, or the adsorption reduction of the strength of solids Describes the properties of polymers in environmental or solvent crazing Analyses the interaction of the highly developed surface of crazed polymers with diverse low- and high-molecular mass components Addresses the instability and self-organisation of surface layers in polymers and diverse polymer systems Presents theoretical speculations concerning the structurally mechanical behaviour of ‘a rigid coating on a soft substratum’ (RCSS) systems Assesses the stress–strain properties of the thin surface layers of polymers and the nanometric coatings deposited on their surfaces Highlights the efficacy of the approaches developed for RCSS systems for the analysis and description of natural phenomena Details the applied aspects of surface phenomena in the structurally mechanical behaviour of polymers Thus, Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers provides a useful framework for the development of new and innovative polymer-based materials.

Structural Glasses and Supercooled Liquids

Author : Peter G. Wolynes,Vassiliy Lubchenko
Publisher : John Wiley & Sons
Page : 422 pages
File Size : 46,7 Mb
Release : 2012-03-12
Category : Science
ISBN : 9781118202418

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Structural Glasses and Supercooled Liquids by Peter G. Wolynes,Vassiliy Lubchenko Pdf

With contributions from 24 global experts in diverse fields, and edited by world-recognized leaders in physical chemistry, chemical physics and biophysics, Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications presents a modern, complete survey of glassy phenomena in many systems based on firmly established characteristics of the underlying molecular motions as deduced by first principle theoretical calculations, or with direct/single-molecule experimental techniques. A well-rounded view of a variety of disordered systems where cooperative phenomena, which are epitomized by supercooled liquids, take place is provided. These systems include structural glasses and supercooled liquids, polymers, complex liquids, protein conformational dynamics, and strongly interacting electron systems with quenched/self-generated disorder. Detailed calculations and reasoned arguments closely corresponding with experimental data are included, making the book accessible to an educated non-expert reader.

Advances in Chemical Physics, Volume 137

Author : Stuart A. Rice
Publisher : John Wiley & Sons
Page : 266 pages
File Size : 42,6 Mb
Release : 2008-04-30
Category : Science
ISBN : 9780470238073

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Advances in Chemical Physics, Volume 137 by Stuart A. Rice Pdf

The Advances in Chemical Physics series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. This special volume focuses on atoms and photos near meso- and nanobodies, an important area of nontechnology. Nanoscale particles are those between 1 and 100 nm, and they obey neither the laws of quantum physics nor of classical physics due to an extensive delocalization of the valence electrons, which can vary depending on size. This means that different physical properties can be obtained from the same atoms or molecules existing in a nanoscale particle size due entirely to differing sizes and shapes. Nanostructured materials have unique optical, magnetic, and electronic properties depending on the size and shape of the nanomaterials. A great deal of interest has surfaced in this arena as of late due to the potential technological applications.

Structure and Mobility in Molecular and Atomic Glasses

Author : James M. O'REILLY
Publisher : Unknown
Page : 358 pages
File Size : 54,6 Mb
Release : 1981
Category : Electronic
ISBN : OCLC:227513477

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Structure and Mobility in Molecular and Atomic Glasses by James M. O'REILLY Pdf

Partial Contents: The Glassy State: A Summary of Experimental and Theoretical Methodology; Theory: Polymer Glasses; A Multiparameter Approach for Structural Recovery of Glasses and Its Implication for Their Physical Properties; Enthalpy Recovery in Pressure-Vitrified and Mechanically Stressed Polymeric Glasses; Fourier Transform Infrared Spectroscopy of Amorphous Polymers; High-Resolution Solid-State NMR of Glasses; Molecular Dynamics Simulation of the Glass Transition; The Glass Transition: Comparison of Computer Simulation and Laboratory Studies; Comparison and Analysis of Relaxation Processes at the Glass Transition Temperature; Changes in Photoelectronic Behavior of Glasses during Structural Relaxation; Laser Light Scattering Studies of Bulk Polymers in the Glass Transition Regime; A New Free-Volume Theory of the Glass Transition; Theory of Glass Quenched from the Melt; Relaxation in Metallic Glasses; Spectroscopy of Glasses; and Glass Transition in the Hard-Sphere Model and Kauzmann's Paradox.

The Physics of Glassy Polymers

Author : R. N. Haward
Publisher : Springer
Page : 620 pages
File Size : 43,9 Mb
Release : 2011-12-09
Category : Science
ISBN : 9401023573

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The Physics of Glassy Polymers by R. N. Haward Pdf

This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.

Hyperbranched Polymers for Biomedical Applications

Author : Abhijit Bandyopadhyay,Srijoni Sengupta,Tamalika Das
Publisher : Springer
Page : 178 pages
File Size : 55,8 Mb
Release : 2017-09-18
Category : Technology & Engineering
ISBN : 9789811065149

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Hyperbranched Polymers for Biomedical Applications by Abhijit Bandyopadhyay,Srijoni Sengupta,Tamalika Das Pdf

This book presents a comprehensive study on a new class of branched polymers, known as hyperbranched polymers (HBPs). It discusses in detail the synthesis strategies for these particular classes of polymers as well as biocompatible and biodegradable HBPs, which are of increasing interest to polymer technologists due to their immense potential in biomedical applications. The book also describes the one-pot synthesis technique for HBPs, which is feasible for large-scale production, as well as HBPs’ structure-property relationship, which makes them superior to their linear counterparts. The alterable functional groups present at the terminal ends of the branches make HBPs promising candidates in the biomedical domain, and the book specifically elaborates on the suitable characteristic properties of each of the potential biological HBPs’ applications. As such, the book offers a valuable reference guide for all scientists and technologists who are interested in using these newly developed techniques to achieve faster and better treatments.

The Physics of Deformation and Fracture of Polymers

Author : A. S. Argon
Publisher : Cambridge University Press
Page : 535 pages
File Size : 48,5 Mb
Release : 2013-03-07
Category : Science
ISBN : 9780521821841

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The Physics of Deformation and Fracture of Polymers by A. S. Argon Pdf

A physical, mechanism-based presentation of the plasticity and fracture of polymers, covering industrial scale applications through to nanoscale biofluidic devices.

Molecular Dynamics of Additives in Polymers

Author : A. L. Kovarski
Publisher : VSP
Page : 292 pages
File Size : 45,9 Mb
Release : 1997
Category : Technology & Engineering
ISBN : 9067642592

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Molecular Dynamics of Additives in Polymers by A. L. Kovarski Pdf

This volume focuses on the dynamical behaviour of low-molecular additives in solid polymer matrixes. It covers: types and models of molecular motion in condensed media; dependence of motional frequency on particle structure and size, temperature, volume and stress; and polymer properties and polymeric structures. Extensive analysis of common regularities of rotational and translational dynamics of molecules introduced into polymers are given. The book also includes experimental techniques for molecular mobility evaluation, and features detailed data on rotational dynamics of additives. It should be of interest to specialists in various fields of polymer physical chemistry and materials science.