Molecular Mobility In Deforming Polymer Glasses

Author : Nikhil Padhye
Publisher : Springer Nature
Page : 111 pages
File Size : 53,8 Mb
Release : 2021-10-15
Category : Science
ISBN : 9783030825591

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Molecular Mobility in Deforming Polymer Glasses by Nikhil Padhye Pdf

This book bridges disparate fields in an exploration of the phenomena and applications surrounding molecular mobility in glassy materials experiencing inelastic deformation. The subjects of plastic deformation and polymer motion/interdiffusion currently belong to the two different fields of continuum mechanics and polymer physics, respectively. However, molecular motion associated with plastic deformation is a key ingredient to gain fundamental understanding, both at the macroscopic and microscopic level. This short monograph provides necessary background in the aforementioned fields before addressing the topic of molecular mobility accompanied by macroscopic inelastic deformation in an accessible and easy-to-understand manner. A new phenomenon of solid-state deformation-induced bonding in polymers is discussed in detail, along with some broad implications in several manufacturing sectors. Open questions pertaining to mechanisms, mechanics, and modeling of deformation-induced bonding in polymers are presented. The book’s clear language and careful explanations will speak to readers of diverse backgrounds.

Author : Connie B. Roth
Publisher : CRC Press
Page : 752 pages
File Size : 42,5 Mb
Release : 2016-12-12
Category : Science
ISBN : 9781315305134

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Polymer Glasses by Connie B. Roth Pdf

"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Author : Hans-Henning Kausch
Publisher : Springer Science & Business Media
Page : 288 pages
File Size : 45,7 Mb
Release : 2005-11-18
Category : Technology & Engineering
ISBN : 3540261621

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Intrinsic Molecular Mobility and Toughness of Polymers II by Hans-Henning Kausch Pdf

Author : Jo Perez
Publisher : Routledge
Page : 177 pages
File Size : 50,5 Mb
Release : 2018-04-27
Category : Science
ISBN : 9781351424516

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Physics and Mechanics of Amorphous Polymers by Jo Perez Pdf

Topics covered in this text include: structural aspects of polymers; molecular mobility in amorphous solid polymers; non-elastic deformation of solid amorphous polymers; mechanical experiments; interpretation of results; physical ageing of amorphous polymers; and glass transition.

Author : Connie B. Roth
Publisher : CRC Press
Page : 573 pages
File Size : 46,9 Mb
Release : 2016-12-12
Category : Science
ISBN : 9781315305141

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Polymer Glasses by Connie B. Roth Pdf

"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Author : Hans-Henning Kausch
Publisher : Springer Science & Business Media
Page : 420 pages
File Size : 42,9 Mb
Release : 2005-12-01
Category : Technology & Engineering
ISBN : 3540261559

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Intrinsic Molecular Mobility and Toughness of Polymers I by Hans-Henning Kausch Pdf

Ce livre historique peut contenir de nombreuses coquilles et du texte manquant. Les acheteurs peuvent generalement telecharger une copie gratuite scannee du livre original (sans les coquilles) aupres de l'editeur. Non reference. Non illustre. 1838 edition. Extrait: ...a tetat naissant, et particularite relative a ce principe dans quelques legumineuses. Afin de rechercher si les memes proprietes existaient dans l'amidon, a l'etat naissant ou tres jeune, j'examinai cette secretion au moment ou elle se montre dans les cotyledons encore baignes par le liquide sucre de l'ovule du pisum sativum. Ses grains tres petits alors, offrent aussi les caracteres physiques et chimiques qui precedent, et ceux que nous exposerons plus loin; une particularite remarquable dans leurs formes a ete decrite et figuree pi. 4 fig-' ' ' Dans les cotyledons de la feve commune, on trouve des grains d'amidon plus sinueux encore. L'amidon extrait des haricots et des lentilles presente des grains qui se dessinent par des contours moins sinueux que les precedens. Enfin, l'amidon en tres petite quantite dans les-graines de Colutea arborescens (Baguenaudier), est en grains excessivement petits, qui sont arrondis quoique plus ou moins irreguliers. X. Botak.--Stptrmlre. i La configuration sinueuse, contournee ou vermiforme, observee dans plusieurs graines des legumineuses, ne se retrouve donc pas dans toutes au meme degre; elle offrfun exemple de plus des varietes de formes que peut affecter l'amidon dans les circonstances legerement variables, ou se produit cette secretion, sans que les caracteres physiques essentiels ni la composition chimique soient differentes.;; ..., r..', ', ., Amidon completement epure, ...

Author : Maxim Arzhakov
Publisher : CRC Press
Page : 183 pages
File Size : 48,8 Mb
Release : 2019-01-30
Category : Science
ISBN : 9780429534737

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Relaxation in Physical and Mechanical Behavior of Polymers by Maxim Arzhakov Pdf

Explores the nature of relaxation phenomena in polymers on the basis of time-temperature equivalence. Its role in the physical and mechanical behavior of polymers materials and fundamentals of thermoplastics processing are discussed. Four appendixes detail thermo-mechanical methods to study relaxation in polymers, structure of both amorphous and semi-crystalline polymers, and unified approach to describe deformation of polymeric materials.

Author : James M. O'REILLY
Publisher : Unknown
Page : 358 pages
File Size : 44,8 Mb
Release : 1981
Category : Electronic
ISBN : OCLC:227513477

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Structure and Mobility in Molecular and Atomic Glasses by James M. O'REILLY Pdf

Partial Contents: The Glassy State: A Summary of Experimental and Theoretical Methodology; Theory: Polymer Glasses; A Multiparameter Approach for Structural Recovery of Glasses and Its Implication for Their Physical Properties; Enthalpy Recovery in Pressure-Vitrified and Mechanically Stressed Polymeric Glasses; Fourier Transform Infrared Spectroscopy of Amorphous Polymers; High-Resolution Solid-State NMR of Glasses; Molecular Dynamics Simulation of the Glass Transition; The Glass Transition: Comparison of Computer Simulation and Laboratory Studies; Comparison and Analysis of Relaxation Processes at the Glass Transition Temperature; Changes in Photoelectronic Behavior of Glasses during Structural Relaxation; Laser Light Scattering Studies of Bulk Polymers in the Glass Transition Regime; A New Free-Volume Theory of the Glass Transition; Theory of Glass Quenched from the Melt; Relaxation in Metallic Glasses; Spectroscopy of Glasses; and Glass Transition in the Hard-Sphere Model and Kauzmann's Paradox.

Author : Yukihiro Ozaki,Harumi Sato
Publisher : John Wiley & Sons
Page : 500 pages
File Size : 50,7 Mb
Release : 2022-03-14
Category : Science
ISBN : 9783527348336

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Spectroscopic Techniques for Polymer Characterization by Yukihiro Ozaki,Harumi Sato Pdf

An insightful exploration of cutting-edge spectroscopic techniques in polymer characterization In Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications, a team of distinguished chemists delivers a comprehensive exploration of the vast potential of spectroscopic characterization techniques in polymer research. The book offers a concise outline of the principles, advantages, instrumentation, experimental techniques, and noteworthy applications of cutting-edge spectroscopy. Covering a wide range of polymers, from nylon to complex polymeric nanocomposites, the author presents recent developments in polymer science to polymer, analytical, and material chemists, assisting them in keeping track of the progress in modern spectroscopy. Spectroscopic Techniques for Polymer Characterization contains contributions from pioneers in modern spectroscopic techniques from around the world. The included materials bridge the gap between spectroscopists, polymer scientists, and engineers in academia and industry. The book also offers: A thorough introduction to the progress in spectroscopic techniques, including polymer spectroscopy and near-infrared spectroscopy Comprehensive explorations of topical polymers studied by spectroscopy, including polymer thin films, fluoropolymers, polymer solutions, conductive polymers Practical discussions of infrared imaging, near-infrared imaging, two-dimensional correlation spectroscopy, and far-ultraviolet spectroscopy In-depth examinations of spectroscopic studies of weak hydrogen bonding in polymers Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications is a must-read reference for polymer, analytical, and physical chemists, as well as materials scientists and spectroscopists seeking a one-stop resource for polymer characterization using spectroscopic analyses.

Author : L. Volynskii,N. F. Bakeev
Publisher : CRC Press
Page : 509 pages
File Size : 44,5 Mb
Release : 2018-09-03
Category : Science
ISBN : 9781315359946

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Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers by L. Volynskii,N. F. Bakeev Pdf

Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers explores the role of various surface phenomena in the structural and mechanical behaviour of amorphous and semicrystalline polymers. This book: Discusses the development of the interfacial surface in the deformation of polymers Examines the healing of interfacial surfaces in polymers Inspects the structure and properties of polymers in thin films and surface layers Evaluates the mechanism of inelastic deformation in glassy amorphous polymers Investigates strain softening and the phenomena taking place upon deformation of polymers in active liquid media Covers the Rehbinder effect, or the adsorption reduction of the strength of solids Describes the properties of polymers in environmental or solvent crazing Analyses the interaction of the highly developed surface of crazed polymers with diverse low- and high-molecular mass components Addresses the instability and self-organisation of surface layers in polymers and diverse polymer systems Presents theoretical speculations concerning the structurally mechanical behaviour of ‘a rigid coating on a soft substratum’ (RCSS) systems Assesses the stress–strain properties of the thin surface layers of polymers and the nanometric coatings deposited on their surfaces Highlights the efficacy of the approaches developed for RCSS systems for the analysis and description of natural phenomena Details the applied aspects of surface phenomena in the structurally mechanical behaviour of polymers Thus, Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers provides a useful framework for the development of new and innovative polymer-based materials.

Author : Anonim
Publisher : ScholarlyEditions
Page : 284 pages
File Size : 54,6 Mb
Release : 2012-01-09
Category : Technology & Engineering
ISBN : 9781464922886

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Acrylates: Advances in Research and Application: 2011 Edition by Anonim Pdf

Acrylates: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Acrylates. The editors have built Acrylates: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Acrylates in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Acrylates: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Author : Anonim
Publisher : Unknown
Page : 278 pages
File Size : 41,5 Mb
Release : 1980
Category : Glass-reinforced plastics
ISBN : UOM:39015049074076

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Structure and Motion in Polymer Glasses by Anonim Pdf

Author : Friedrich Kremer,Alois Loidl
Publisher : Springer
Page : 409 pages
File Size : 50,9 Mb
Release : 2018-07-20
Category : Science
ISBN : 9783319727066

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The Scaling of Relaxation Processes by Friedrich Kremer,Alois Loidl Pdf

The dielectric properties especially of glassy materials are nowadays explored at widely varying temperatures and pressures without any gap in the spectral range from μHz up to the Infrared, thus covering typically 20 decades or more. This extraordinary span enables to trace the scaling and the mutual interactions of relaxation processes in detail, e.g. the dynamic glass transition and secondary relaxations, but as well far infrared vibrations, like the Boson peak. Additionally the evolution of intra-molecular interactions in the course of the dynamic glass transition is also well explored by (Fourier Transform) Infrared Spectroscopy. This volume within 'Advances in Dielectrics' summarizes this knowledge and discusses it with respect to the existing and often competing theoretical concepts.

Author : Anonim
Publisher : Newnes
Page : 7752 pages
File Size : 53,8 Mb
Release : 2012-12-05
Category : Technology & Engineering
ISBN : 9780080878621

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Polymer Science: A Comprehensive Reference by Anonim Pdf

The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)

Author : Richard A. Pethrick
Publisher : CRC Press
Page : 346 pages
File Size : 55,5 Mb
Release : 1998-11-26
Category : Technology & Engineering
ISBN : 9057023202

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Polymer Yearbook 15 by Richard A. Pethrick Pdf

This volume contains reviews on state-of-the-art Japanese research presented in the annual Spring and Autumn meetings of the Japanese Polymer Science Society. The aim of this section is to make information on the progress of Japanese Polymer Science, and on topics of current interest to polymer scientists in Japan, more easily available worldwide.