Analytical Pyrolysis Of Synthetic Organic Polymers

Author : Serban C. Moldoveanu
Publisher : Elsevier
Page : 714 pages
File Size : 42,8 Mb
Release : 2005-01-20
Category : Science
ISBN : 9780080455860

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Analytical Pyrolysis of Synthetic Organic Polymers by Serban C. Moldoveanu Pdf

Analytical Pyrolysis of Synthetic Organic Polymers is a follow-up to Analytical Pyrolysis of Natural Organic Polymers, which is volume 20 of the series. The main focus of the book is on practical applications of analytical pyrolysis in synthetic organic polymer identification and characterization. The first part of the book has five chapters including an introduction, a discussion on physico-chemistry of thermal degradation of synthetic polymers and on instrumentation used in analytical pyrolysis, a chapter discussing what type of information can be obtained from analytical pyrolysis, and a chapter dedicated to the analysis and characterization of synthetic polymers. The second part systematically covers the analytical pyrolysis of various classes of synthetic polymers. Some theoretical background for the understanding of polymer structure using analytical pyrolysis is also discussed. * Includes broad coverage of organic synthetic macromolecules * Focuses on physico-chemistry of thermal degradation, and the analytical pyrolysis of various classes of synthetic polymers * Is well written and suitable for both researchers and chemists working in analytical chemistry or in synthetic polymers

Author : Serban C. Moldoveanu
Publisher : Elsevier Science
Page : 714 pages
File Size : 52,9 Mb
Release : 2005-03-17
Category : Science
ISBN : 0444512926

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Analytical Pyrolysis of Synthetic Organic Polymers by Serban C. Moldoveanu Pdf

Analytical Pyrolysis of Synthetic Organic Polymers is a follow-up to Analytical Pyrolysis of Natural Organic Polymers, which is volume 20 of the series. The main focus of the book is on practical applications of analytical pyrolysis in synthetic organic polymer identification and characterization. The first part of the book has five chapters including an introduction, a discussion on physico-chemistry of thermal degradation of synthetic polymers and on instrumentation used in analytical pyrolysis, a chapter discussing what type of information can be obtained from analytical pyrolysis, and a chapter dedicated to the analysis and characterization of synthetic polymers. The second part systematically covers the analytical pyrolysis of various classes of synthetic polymers. Some theoretical background for the understanding of polymer structure using analytical pyrolysis is also discussed. * Includes broad coverage of organic synthetic macromolecules * Focuses on physico-chemistry of thermal degradation, and the analytical pyrolysis of various classes of synthetic polymers * Is well written and suitable for both researchers and chemists working in analytical chemistry or in synthetic polymers

Author : Peter Kusch
Publisher : BoD – Books on Demand
Page : 104 pages
File Size : 50,8 Mb
Release : 2019-02-13
Category : Science
ISBN : 9781789849585

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Analytical Pyrolysis by Peter Kusch Pdf

Analytical pyrolysis deals with the structural identification and quantitation of pyrolysis products with the ultimate aim of establishing the identity of the original material and the mechanisms of its thermal decomposition. The pyrolytic process is carried out in a pyrolyzer interfaced with analytical instrumentation such as gas chromatography (GC), mass spectrometry (MS), gas chromatography coupled with mass spectrometry (GC/MS), or with Fourier-transform infrared spectroscopy (GC/FTIR). By measurement and identification of pyrolysis products, the molecular composition of the original sample can often be reconstructed.This book is the outcome of contributions by experts in the field of pyrolysis and includes applications of the analytical pyrolysis-GC/MS to characterize the structure of synthetic organic polymers and lignocellulosic materials as well as cellulosic pulps and isolated lignins, solid wood, waste particle board, and bio-oil. The thermal degradation of cellulose and biomass is examined by scanning electron micrography, FTIR spectroscopy, thermogravimetry (TG), differential thermal analysis, and TG/MS. The calorimetric determination of high heating values of different raw biomass, plastic waste, and biomass/plastic waste mixtures and their by-products resulting from pyrolysis is described.

Author : S.C. Moldoveanu
Publisher : Elsevier
Page : 640 pages
File Size : 52,7 Mb
Release : 2020-09-12
Category : Science
ISBN : 9780128235539

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Analytical Pyrolysis of Natural Organic Polymers by S.C. Moldoveanu Pdf

Analytical Pyrolysis of Natural Organic Polymers, Second Edition, Volume 20 describes the methodology of analytical pyrolysis, the results of pyrolysis for a variety of biopolymers, and several practical applications of analytical pyrolysis on natural organic polymers and their composite materials. The book describes the results of pyrolysis for biopolymers and some chemically modified natural organic polymers. In addition, the many applications of analytical pyrolysis are covered in detail, including topics such as polymer detection used in forensic science, structure elucidation of specific polymers, and identification of small molecules present in polymers (anti-oxidants, plasticizers, etc.). Assembles all essential information on the pyrolysis of natural polymers in one volume, together with the techniques and instrumentation used Covers advances and developments over the last 20 years, including discussions on the many different types of apparatus commercially available Includes reference lists in every chapter to guide readers on a path to further study

Author : Shin Tsuge,Hajima Ohtani,Chuichi Watanabe
Publisher : Elsevier
Page : 406 pages
File Size : 44,5 Mb
Release : 2011-10-13
Category : Performing Arts
ISBN : 9780444538925

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Pyrolysis - GC/MS Data Book of Synthetic Polymers by Shin Tsuge,Hajima Ohtani,Chuichi Watanabe Pdf

In this data book, both conventional Py-GC/MS where thermal energy alone is used to cause fragmentation of given polymeric materials and reactive Py-GC/MS in the presence of organic alkaline for condensation polymers are compiled. Before going into detailed presentation of the data, however, acquiring a firm grip on the proper understanding about the situation of Py-GC/MS would promote better utilization of the following pyrolysis data for various polymers samples. This book incorporates recent technological advances in analytical pyrolysis methods especially useful for the characterization of 163 typical synthetic polymers. The book briefly reviews the instrumentation available in advanced analytical pyrolysis, and offers guidance to perform effectually this technique combining with gas chromatography and mass spectrometry. Main contents are comprehensive sample pyrograms, thermograms, identification tables, and representative mass spectra (MS) of pyrolyzates for synthetic polymers. This edition also highlights thermally-assisted hydrolysis and methylation technique effectively applied to 33 basic condensation polymers. Coverage of Py-GC/MS data of conventional pyrograms and thermograms of basic 163 kinds of synthetic polymers together with MS and retention index data for pyrolyzates, enabling a quick identification Additional coverage of the pyrograms and their related data for 33 basic condensation polymers obtained by the thermally-assisted hydrolysis and methylation technique All compiled data measured under the same experimental conditions for pyrolysis, gas chromatography and mass spectrometry to facilitate peak identification Surveyable instant information on two facing pages dedicated to the whole data of a given polymer sample

Author : Peter Kusch
Publisher : Unknown
Page : 102 pages
File Size : 48,8 Mb
Release : 2019
Category : Chemistry, Analytic
ISBN : 1789849594

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Analytical Pyrolysis by Peter Kusch Pdf

Analytical pyrolysis deals with the structural identification and quantitation of pyrolysis products with the ultimate aim of establishing the identity of the original material and the mechanisms of its thermal decomposition. The pyrolytic process is carried out in a pyrolyzer interfaced with analytical instrumentation such as gas chromatography (GC), mass spectrometry (MS), gas chromatography coupled with mass spectrometry (GC/MS), or with Fourier-transform infrared spectroscopy (GC/FTIR). By measurement and identification of pyrolysis products, the molecular composition of the original sample can often be reconstructed.This book is the outcome of contributions by experts in the field of pyrolysis and includes applications of the analytical pyrolysis-GC/MS to characterize the structure of synthetic organic polymers and lignocellulosic materials as well as cellulosic pulps and isolated lignins, solid wood, waste particle board, and bio-oil. The thermal degradation of cellulose and biomass is examined by scanning electron micrography, FTIR spectroscopy, thermogravimetry (TG), differential thermal analysis, and TG/MS. The calorimetric determination of high heating values of different raw biomass, plastic waste, and biomass/plastic waste mixtures and their by-products resulting from pyrolysis is described.

Author : Peter Kusch
Publisher : World Scientific
Page : 383 pages
File Size : 43,5 Mb
Release : 2023-08-28
Category : Science
ISBN : 9781800613003

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Pyrolysis-gas Chromatography/mass Spectrometry Of Polymeric Materials (Second Edition) by Peter Kusch Pdf

Readers will find many practical applications of pyrolysis-GC/MS as well as R&D usage in this newly revised and expanded edition. Detailed experimental descriptions for the identification of synthetic polymers and copolymers are included. This volume presents the current state of analytical pyrolysis, and contains full identification of several classes of polymers/copolymers and biopolymers that readers will find helpful. Structures and functions of various types of pyrolyzers are explored, as well as the results of the pyrolysis-gas chromatographic-mass spectrometric identification of synthetic polymers/copolymers and biopolymers at 700°C.Practical applications of this hyphenated technique, detailing the analysis of microplastics, failure analysis in the automotive industry and solutions for technological problems are provided. Numerous practical applications of pyrolysis-GC/MS, for industrial and R&D usage, will be of benefit to Chemists and Engineers, as well as for students of Chemistry and Polymer Sciences.

Author : Karen D. Sam,Thomas P. Wampler
Publisher : CRC Press
Page : 354 pages
File Size : 54,6 Mb
Release : 2021-03-23
Category : Science
ISBN : 9780429574924

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Analytical Pyrolysis Handbook by Karen D. Sam,Thomas P. Wampler Pdf

Analytical pyrolysis allows scientists to use routine laboratory instrumentation for analyzing complex, opaque, or insoluble samples more effectively than other analytical techniques alone. Analytical Pyrolysis Handbook, Third Edition is a practical guide to the application of pyrolysis techniques to various samples and sample types for a diversity of fields including microbiology, forensic science, industrial research, and environmental analysis. The much-anticipated third edition incorporates recent technological advances that increase the technique’s sensitivity to trace elements, improve its reproducibility, and expand its applicability. The book reviews the types of instrumentation available to perform pyrolysis and offers guidance for interfacing instruments and integrating other analytical techniques, including gas chromatography and mass spectrometry. Fully updated with new sample pyrograms, figures, references, and real-world examples, this edition also highlights new areas of application including cultural materials, forensic analysis, and environmental studies. This book illustrates how the latest advances make pyrolysis a practical, cost-effective, reliable, and flexible alternative for increasingly complex sample analyses. Analytical Pyrolysis Handbook, Third Edition is an essential, one-stop guide for determining if pyrolysis meets application-specific needs as well as performing pyrolysis and handling the data obtained.

Author : Shin Tsuge,Hajima Ohtani,Chuichi Watanabe
Publisher : Elsevier
Page : 420 pages
File Size : 45,6 Mb
Release : 2011-08-02
Category : Science
ISBN : 9780444538932

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Pyrolysis - GC/MS Data Book of Synthetic Polymers by Shin Tsuge,Hajima Ohtani,Chuichi Watanabe Pdf

In this data book, both conventional Py-GC/MS where thermal energy alone is used to cause fragmentation of given polymeric materials and reactive Py-GC/MS in the presence of organic alkaline for condensation polymers are compiled. Before going into detailed presentation of the data, however, acquiring a firm grip on the proper understanding about the situation of Py-GC/MS would promote better utilization of the following pyrolysis data for various polymers samples. This book incorporates recent technological advances in analytical pyrolysis methods especially useful for the characterization of 163 typical synthetic polymers. The book briefly reviews the instrumentation available in advanced analytical pyrolysis, and offers guidance to perform effectually this technique combining with gas chromatography and mass spectrometry. Main contents are comprehensive sample pyrograms, thermograms, identification tables, and representative mass spectra (MS) of pyrolyzates for synthetic polymers. This edition also highlights thermally-assisted hydrolysis and methylation technique effectively applied to 33 basic condensation polymers. Coverage of Py-GC/MS data of conventional pyrograms and thermograms of basic 163 kinds of synthetic polymers together with MS and retention index data for pyrolyzates, enabling a quick identification Additional coverage of the pyrograms and their related data for 33 basic condensation polymers obtained by the thermally-assisted hydrolysis and methylation technique All compiled data measured under the same experimental conditions for pyrolysis, gas chromatography and mass spectrometry to facilitate peak identification Surveyable instant information on two facing pages dedicated to the whole data of a given polymer sample

Author : Samuel Leo Madorsky
Publisher : Unknown
Page : 344 pages
File Size : 40,6 Mb
Release : 1964
Category : Polymerization
ISBN : UOM:39015002126483

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Thermal Degradation of Organic Polymers by Samuel Leo Madorsky Pdf

Author : Peter Kusch
Publisher : World Scientific
Page : 268 pages
File Size : 45,8 Mb
Release : 2018-10-08
Category : Science
ISBN : 9781786345776

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Pyrolysis-gas Chromatography: Mass Spectrometry Of Polymeric Materials by Peter Kusch Pdf

The methodology of analytical pyrolysis-GC/MS has been known for several years, but is seldom used in research laboratories and process control in the chemical industry. This is due to the relative difficulty of interpreting the identified pyrolysis products as well as the variety of them. This book contains full identification of several classes of polymers/copolymers and biopolymers that can be very helpful to the user. In addition, the practical applications can encourage analytical chemists and engineers to use the techniques explored in this volume.The structure and the functions of various types of pyrolyzers and the results of the pyrolysis-gas chromatographic-mass spectrometric identification of synthetic polymers/copolymers and biopolymers at 700°C are described. Practical applications of these techniques are also included, detailing the analysis of microplastics, failure analysis in the automotive industry and solutions for technological problems.

Author : C.E.R. Jones
Publisher : Elsevier
Page : 435 pages
File Size : 47,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444601407

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Analytical Pyrolysis by C.E.R. Jones Pdf

Analytical Pyrolysis presents the Proceedings of the Third International Symposium on Analytical Pyrolysis, held in Amsterdam on September 7-9, 1976. It looks at newly emergent techniques in analytical pyrolysis, including pyrolysis mass spectrometry, gas chromatography, thin-layer chromatography, and pyrolysis-gas liquid chromatography. The book also covers topics ranging from automation and microbiology to forensic science and pharmacology, reproducibility and specificity, biochemistry, laser-induced pyrolysis, pyrolytic reaction mechanisms, and polymers. Comprised of 50 chapters, this book begins with a discussion of automatic analysis of tire rubber blends using computer-linked pyrolysis gas chromatography, thermal procedures in coupling with thin-layer chromatography, the role of pyrolysis-gas liquid chromatography in biomedical studies, and the identification of microorganisms by pyrolysis gas-liquid chromatography. It then examines forensic applications of analytical pyrolysis techniques, structure and degradation behavior of synthetic polymers using pyrolysis in combination with field ion mass spectrometry, determination of polysaccharides in fulvic acids by pyrolysis gas chromatography, and application of Curie-point pyrolysis mass spectrometry in fungal taxonomy. The reader is also introduced to pyrolysis mass spectrometry of model compounds labeled with stable isotopes, the use of pyrolysis/gas chromatography to determine the quality of porous polymers of styrene cross-linked with divinyl benzene, and application of pyrohydrolysis for a rapid and accurate determination of halides in silicate rocks and minerals. This volume will benefit students, researchers, chemists, and scientists working in the field of analytical pyrolysis.

Author : Serban C. Moldoveanu
Publisher : Elsevier
Page : 744 pages
File Size : 46,6 Mb
Release : 2009-09-16
Category : Science
ISBN : 0080932150

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Pyrolysis of Organic Molecules by Serban C. Moldoveanu Pdf

Pyrolysis of Organic Molecules with Applications to Health and Environmental Issues, the 28th volume in the Techniques and Instrumentation in Analytical Chemistry series, gives a systematic and comprehensive description of pyrolysis of non-polymeric organic molecules. Pyrolysis is involved in many practical applications as well as in many common human activities, but harmful compounds can be generated in the process. The study of pyrolysis and of the formation of undesirable compounds as a result of pyrolytic processes is of considerable interest to chemists, chemical engineers, and toxicologists. Pyrolysis results for compounds not previously studied or reported Updated information from a large body of results published on pyrolysis of individual compounds or classes of compounds Information on mechanisms and kinetics of numerous pyrolytic processes

Author : Mahmood Barbooti
Publisher : CRC Press
Page : 604 pages
File Size : 48,8 Mb
Release : 2015-04-15
Category : Science
ISBN : 9781482262643

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Environmental Applications of Instrumental Chemical Analysis by Mahmood Barbooti Pdf

This book is a comprehensive review of the instrumental analytical methods and their use in environmental monitoring site assessment and remediation follow-up operations. The increased concern about environmental issues such as water pollution, air pollution, accumulation of pollutants in food, global climate change, and effective remediation processes necessitate the precise determination of various types of chemicals in environmental samples. In general, all stages of environmental work start with the evaluation of organic and inorganic environmental samples. This important book furnishes the fundamentals of instrumental chemical analysis methods to various environmental applications and also covers recent developments in instrumental chemical methods. Covering a wide variety of topics in the field, the book: • Presents an introduction to environmental chemistry • Presents the fundamentals of instrumental chemical analysis methods that are used mostly in the environmental work. • Examines instrumental methods of analysis including UV/Vis, FTIR, atomic absorption, induced coupled plasma emission, electrochemical methods like potentiometry, voltametry, coulometry, and chromatographic methods such as GC and HPLC • Presents newly introduced chromatographic methodologies such as ion electrophoresis, and combinations of chromatography with pyrolysis methods are given • Discusses selected methods for the determinations of various pollutants in water, air, and land Readers will gain a general review of modern instrumental method of chemical analysis that is useful in environmental work and will learn how to select methods for analyzing certain samples. Analytical instrumentation and its underlying principles are presented, along with the types of sample for which each instrument is best suited. Some noninstrumental techniques, such as colorimetric detection tubes for gases and immnosassays, are also discussed.

Author : Luigia Sabbatini,Inez Dorothé van der Werf
Publisher : Walter de Gruyter GmbH & Co KG
Page : 488 pages
File Size : 44,7 Mb
Release : 2020-02-24
Category : Technology & Engineering
ISBN : 9783110457537

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Chemical Analysis in Cultural Heritage by Luigia Sabbatini,Inez Dorothé van der Werf Pdf

Chemical Analysis provides non invasive and micro-analytical techniques for the investigation of cultural heritage materials. The tools and techniques, discussed by experts in the field, are of universal, sensitive and multi-component nature.