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Author : D. M. P. Mingos,David J. Wales
Publisher : Unknown
Page : 344 pages
File Size : 51,9 Mb
Release : 1990
Category : Science
ISBN : STANFORD:36105030842707
Author : Guillermo Gonzalez-Moraga
Publisher : Springer Science & Business Media
Page : 310 pages
File Size : 41,6 Mb
Release : 2013-11-09
Category : Science
ISBN : 9783642859267
Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.
Author : Duward F. Shriver,Herbert D. Kaesz,Richard D. Adams
Publisher : Wiley-VCH
Page : 456 pages
File Size : 52,8 Mb
Release : 1990
Category : Science
ISBN : UOM:39015021543395
Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR
Author : Paul-Gerhard Reinhard,Eric Suraud
Publisher : John Wiley & Sons
Page : 341 pages
File Size : 48,6 Mb
Release : 2008-07-11
Category : Science
ISBN : 9783527621019
Clusters as mesoscopic particles represent an intermediate state of matter between single atoms and solid material. The tendency to miniaturise technical objects requires knowledge about systems which contain a "small" number of atoms or molecules only. This is all the more true for dynamical aspects, particularly in relation to the qick development of laser technology and femtosecond spectroscopy. Here, for the first time is a highly qualitative introduction to cluster physics. With its emphasis on cluster dynamics, this will be vital to everyone involved in this interdisciplinary subject. The authors cover the dynamics of clusters on a broad level, including recent developments of femtosecond laser spectroscopy on the one hand and time-dependent density functional theory calculations on the other.
Author : Paul J. Dyson,J. Scott McIndoe
Publisher : CRC Press
Page : 180 pages
File Size : 51,8 Mb
Release : 2018-10-03
Category : Science
ISBN : 9781482283075
Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Author : L.J. de Jongh
Publisher : Springer Science & Business Media
Page : 326 pages
File Size : 42,5 Mb
Release : 2013-03-09
Category : Science
ISBN : 9789401512947
On Friday, February 20, 1980, I had the pleasure to be present at the inaugural lecture of my colleague Jan Reedijk, who had just been named at the Chair of Inorganic Chemistry of Leiden University. According to tradition, the ceremony took place in the impressive Hall of the old University Academy Building. In the course of his lecture, Jan mentioned a number of recent developments in chemistry which had struck him as particularly important or interesting. Among those was the synthesis of large metal cluster compounds, and, to my luck, he showed a slide ofthe molecular structure of [PtI9(C)b]4-. (To my luck, since at traditional Leiden University it is quite unusual to show slides at such ceremonies.) This constituted my first acquaintance with this exciting new class of materials. I became immediately fascinated by this molecule, partly because of the esthetic beauty of its fivefold symmetry, partly because as a physicist it struck me that it could be visualized as an "embryonically small" metal particle, embedded in a shell of CO ligands.
Author : Phuong Mai Dinh,Paul-Gerhard Reinhard,Eric Suraud
Publisher : John Wiley & Sons
Page : 258 pages
File Size : 50,5 Mb
Release : 2013-09-30
Category : Science
ISBN : 9783527675708
Filling the need for a solid textbook, this short primer in cluster science is ideal for a one-semester lecture for advanced undergraduate students. It is based on a series of lectures given by the well-established and recognized authors for the past ten years. The book covers both the basics of the domain as well as up-to-date developments. It can be divided roughly into two parts. The first three chapters introduce basic concepts of cluster science. Chapter 1 provides a general introduction, complemented by chapter 2 on experimental and chapter 3 on theoretical aspects. The second half of the book is devoted to a systematic presentation of free cluster properties, and to a thorough discussion of the impact of clusters in other domains of science. These explicitly worked-out links between cluster physics and other research areas are unique both in terms of fundamental aspects and of applications, and cannot be found elsewhere in the literature. Also suitable for researchers outside of the field looking for an introduction to cluster science.
Author : Hellmut Haberland
Publisher : Springer Science & Business Media
Page : 435 pages
File Size : 40,8 Mb
Release : 2013-11-11
Category : Science
ISBN : 9783642843297
Clusters of Atoms and Molecules I is devoted to theoretical concepts and experimental techniques important in the rapidly expanding field of cluster science. Cluster properties are dicussed for clusters composed of alkali metals, semiconductors, transition metals, carbon, oxides and halides of alkali metals, rare gases, and neutral molecules. The book contains several well-integrated treatments, all prepared by experts. Each contribution starts out as simple as possible and ends with the latest results, so that the book can serve as a text for a course, an introduction into the field, or as a reference book for the expert.
Author : R.A. Mackay
Publisher : CRC Press
Page : 625 pages
File Size : 40,7 Mb
Release : 2017-12-21
Category : Science
ISBN : 9781482268409
This popular and comprehensive textbook provides all the basic information on inorganic chemistry that undergraduates need to know. For this sixth edition, the contents have undergone a complete revision to reflect progress in areas of research, new and modified techniques and their applications, and use of software packages. Introduction to Modern Inorganic Chemistry begins by explaining the electronic structure and properties of atoms, then describes the principles of bonding in diatomic and polyatomic covalent molecules, the solid state, and solution chemistry. Further on in the book, the general properties of the periodic table are studied along with specific elements and groups such as hydrogen, the 's' elements, the lanthanides, the actinides, the transition metals, and the "p" block. Simple and advanced examples are mixed throughout to increase the depth of students' understanding. This edition has a completely new layout including revised artwork, case study boxes, technical notes, and examples. All of the problems have been revised and extended and include notes to assist with approaches and solutions. It is an excellent tool to help students see how inorganic chemistry applies to medicine, the environment, and biological topics.
Author : D.M.P. Mingos
Publisher : Springer
Page : 211 pages
File Size : 43,6 Mb
Release : 2014-03-12
Category : Science
ISBN : 3662148153
It is 25 years since the seminal papers describing the relationships between the skeletal geometrics and closed shell electronic requirements of metal clusters were originally published. The electron counting rules which developed from these papers, are now to be found in all undergraduate inorganic textbooks. This volume provides a contemporary account of recent applications of the methodology and the mathematical foundations of the rules. In addition it describes how it is possible to accomondate acception to the rules within a wider framework. The authors are the foremost authorities in the field and give a broad introduction to the area.
Author : Leonard Kaufman,Peter J. Rousseeuw
Publisher : Wiley-Interscience
Page : 376 pages
File Size : 54,6 Mb
Release : 1990-03-22
Category : Mathematics
ISBN : UCSD:31822005118112
Partitioning around medoids (Program PAM). Clustering large applications (Program CLARA). Fuzzy analysis (Program FANNY). Agglomerative Nesting (Program AGNES). Divisive analysis (Program DIANA). Monothetic analysis (Program MONA). Appendix.
Author : Thomas Fehlner,Jean-Francois Halet,Jean-Yves Saillard
Publisher : Cambridge University Press
Page : 388 pages
File Size : 53,8 Mb
Release : 2007-07-05
Category : Science
ISBN : 0521852366
Describes the structure and bonding of clusters with an approach to solid-state materials, effectively bridging the conceptual gap between them.
Author : Attila Szabo,Neil S. Ostlund
Publisher : Courier Corporation
Page : 480 pages
File Size : 53,6 Mb
Release : 2012-06-08
Category : Science
ISBN : 9780486134598
This graduate-level text explains the modern in-depth approaches to the calculation of electronic structure and the properties of molecules. Largely self-contained, it features more than 150 exercises. 1989 edition.
Author : Frank Jensen
Publisher : John Wiley & Sons
Page : 664 pages
File Size : 55,9 Mb
Release : 2016-12-14
Category : Science
ISBN : 9781118825952
Introduction to Computational Chemistry 3rd Edition provides a comprehensive account of the fundamental principles underlying different computational methods. Fully revised and updated throughout to reflect important method developments and improvements since publication of the previous edition, this timely update includes the following significant revisions and new topics: Polarizable force fields Tight-binding DFT More extensive DFT functionals, excited states and time dependent molecular properties Accelerated Molecular Dynamics methods Tensor decomposition methods Cluster analysis Reduced scaling and reduced prefactor methods Additional information is available at: www.wiley.com/go/jensen/computationalchemistry3
Author : Ruren Xu,Yan Xu
Publisher : Elsevier
Page : 808 pages
File Size : 42,5 Mb
Release : 2017-02-11
Category : Technology & Engineering
ISBN : 9780444635952
Modern Inorganic Synthetic Chemistry, Second Edition captures, in five distinct sections, the latest advancements in inorganic synthetic chemistry, providing materials chemists, chemical engineers, and materials scientists with a valuable reference source to help them advance their research efforts and achieve breakthroughs. Section one includes six chapters centering on synthetic chemistry under specific conditions, such as high-temperature, low-temperature and cryogenic, hydrothermal and solvothermal, high-pressure, photochemical and fusion conditions. Section two focuses on the synthesis and related chemistry problems of highly distinct categories of inorganic compounds, including superheavy elements, coordination compounds and coordination polymers, cluster compounds, organometallic compounds, inorganic polymers, and nonstoichiometric compounds. Section three elaborates on the synthetic chemistry of five important classes of inorganic functional materials, namely, ordered porous materials, carbon materials, advanced ceramic materials, host-guest materials, and hierarchically structured materials. Section four consists of four chapters where the synthesis of functional inorganic aggregates is discussed, giving special attention to the growth of single crystals, assembly of nanomaterials, and preparation of amorphous materials and membranes. The new edition’s biggest highlight is Section five where the frontier in inorganic synthetic chemistry is reviewed by focusing on biomimetic synthesis and rationally designed synthesis. Focuses on the chemistry of inorganic synthesis, assembly, and organization of wide-ranging inorganic systems Covers all major methodologies of inorganic synthesis Provides state-of-the-art synthetic methods Includes real examples in the organization of complex inorganic functional materials Contains more than 4000 references that are all highly reflective of the latest advancement in inorganic synthetic chemistry Presents a comprehensive coverage of the key issues involved in modern inorganic synthetic chemistry as written by experts in the field
