Iron Catalysis Ii

Author : Eike Bauer
Publisher : Springer
Page : 361 pages
File Size : 50,7 Mb
Release : 2015-07-23
Category : Science
ISBN : 9783319193960

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Iron Catalysis II by Eike Bauer Pdf

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Author : Bernd Plietker
Publisher : John Wiley & Sons
Page : 295 pages
File Size : 53,5 Mb
Release : 2008-09-08
Category : Science
ISBN : 9783527623280

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Iron Catalysis in Organic Chemistry by Bernd Plietker Pdf

This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.

Author : Bernd Plietker
Publisher : Springer
Page : 220 pages
File Size : 44,7 Mb
Release : 2011-01-03
Category : Science
ISBN : 9783642146701

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Iron Catalysis by Bernd Plietker Pdf

Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.

Author : Jose M Palomo
Publisher : World Scientific
Page : 350 pages
File Size : 52,9 Mb
Release : 2021-03-15
Category : Science
ISBN : 9781786349637

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Iron Catalysis: Design And Applications by Jose M Palomo Pdf

Iron Catalysis: Design and Applications is an exciting new book that takes readers inside the world of iron catalysis guided by international catalysis expert, Dr Jose M Palomo. Iron is the most abundant metal in the planet, cost-effective, environmentally friendly, with an easily manipulated remediation process. In the last few years the use of this nonprecious metal has gained extraordinary attention particularly for its potential as a catalyst in different areas. This book compiles a series of chapters describing the most significant advances in the last few years since the design of different iron catalysts and nanocatalysts and iron-containing artificial and natural enzymes. The chapters also cover its application in different areas of interest such as organic synthesis, environmental remediation, enzyme-like activities or the creation of novel types of electrodes for battery design.

Author : Robertus J. M. Klein Gebbink,Marc-Etienne Moret
Publisher : John Wiley & Sons
Page : 610 pages
File Size : 45,6 Mb
Release : 2019-04-29
Category : Technology & Engineering
ISBN : 9783527340613

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Non-Noble Metal Catalysis by Robertus J. M. Klein Gebbink,Marc-Etienne Moret Pdf

An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals?enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes. Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns. Providing essential conceptual and practical exploration, this valuable resource: -Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications -Highlights the multiple advantages of using non-noble metals in homogenous catalysis -Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry -Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.

Author : R. Morris Bullock
Publisher : John Wiley & Sons
Page : 296 pages
File Size : 46,8 Mb
Release : 2011-08-02
Category : Science
ISBN : 9783527632404

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Catalysis without Precious Metals by R. Morris Bullock Pdf

Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. An essential copanion for organic and catalytic chemists, as well as those working with/on organometallics and graduate students. From the contents: * Catalysis Involving the H' Transfer Reactions of First-Row Transition Metals * Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Complexes * Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis * Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions * Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes * Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions * Development of Molecular Electrocatalysts for H2 Oxidation and Production Based on Inexpensive Metals * Nickel-Catalyzed Reductinve Couplings and Cyclizations * Copper-Catalyzed Ligand Promoted Ullmann-Type Coupling Reactions * Copper-Catalyzed Azide-Alkyne Cycloaddition * "Frustrated Lewis Pairs": A Metal-Free Strategy for Hydrogenation Catalysis

Author : S. Ted Oyama
Publisher : Elsevier
Page : 528 pages
File Size : 42,8 Mb
Release : 2011-10-13
Category : Technology & Engineering
ISBN : 0080558011

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Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis by S. Ted Oyama Pdf

The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Author : Arimasa Matsumoto
Publisher : Springer
Page : 84 pages
File Size : 51,7 Mb
Release : 2014-07-08
Category : Science
ISBN : 9784431549284

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Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation by Arimasa Matsumoto Pdf

Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.

Author : Uwe Schneider,Stephen Thomas
Publisher : Royal Society of Chemistry
Page : 431 pages
File Size : 41,6 Mb
Release : 2020-10-30
Category : Technology & Engineering
ISBN : 9781788011181

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Catalysis with Earth-abundant Elements by Uwe Schneider,Stephen Thomas Pdf

Considering the limited resources of our planet, earth-abundant elements will have to be explored increasingly in the future. This book highlights the uses of the most earth-abundant elements in catalysis and will be of interest to graduates, academic researchers and practitioners in catalysis.

Author : Pher G. Andersson
Publisher : John Wiley & Sons
Page : 375 pages
File Size : 53,7 Mb
Release : 2012-05-14
Category : Science
ISBN : 9783527330973

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Innovative Catalysis in Organic Synthesis by Pher G. Andersson Pdf

C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.

Author : Piet W.N.M. van Leeuwen,Carmen Claver
Publisher : Springer Nature
Page : 460 pages
File Size : 41,9 Mb
Release : 2020-07-01
Category : Science
ISBN : 9783030458232

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Recent Advances in Nanoparticle Catalysis by Piet W.N.M. van Leeuwen,Carmen Claver Pdf

This book provides an overview of the latest developments in the field of nanoparticle catalysis. It not only discusses established topics in detail, but also explores several emerging topics. Catalysis with nanoparticles is expanding exponentially and is attracting significant interest due to the many exciting findings being reported. Mastering the synthesis, characterization, stabilization and use of these catalysts offers numerous possibilities that far exceed those of classic heterogeneous and homogeneous catalysis.

Author : Wilson D. Shafer,Gary Jacobs
Publisher : MDPI
Page : 414 pages
File Size : 45,6 Mb
Release : 2020-06-23
Category : Science
ISBN : 9783039283880

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Iron and Cobalt Catalysts by Wilson D. Shafer,Gary Jacobs Pdf

Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use these metals: biomass-to-liquids (BTL), coal-to-liquids (CTL), natural gas-to-liquids (GTL), water-gas-shift, alcohol synthesis, alcohol steam reforming, polymerization processes, cross-coupling reactions, and photocatalyst activated reactions. A vast number of materials are produced from these processes, including oil, lubricants, waxes, diesel and jet fuels, hydrogen (e.g., fuel cell applications), gasoline, rubbers, plastics, alcohols, pharmaceuticals, agrochemicals, feed-stock chemicals, and other alternative materials. However, given the true complexities of the variables involved in these processes, many key mechanistic issues are still not fully defined or understood. This Special Issue of Catalysis will be a collaborative effort to combine current catalysis research on these metals from experimental and theoretical perspectives on both heterogeneous and homogeneous catalysts. We welcome contributions from the catalysis community on catalyst characterization, kinetics, reaction mechanism, reactor development, theoretical modeling, and surface science.

Author : Boy Cornils,Wolfgang A. Herrmann,Matthias Beller,Rocco Paciello
Publisher : John Wiley & Sons
Page : 1872 pages
File Size : 52,9 Mb
Release : 2017-09-05
Category : Science
ISBN : 9783527651764

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Applied Homogeneous Catalysis with Organometallic Compounds by Boy Cornils,Wolfgang A. Herrmann,Matthias Beller,Rocco Paciello Pdf

The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.

Author : Arkaitz Correa
Publisher : Springer
Page : 338 pages
File Size : 44,5 Mb
Release : 2016-11-26
Category : Science
ISBN : 9783319497846

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Ni- and Fe-Based Cross-Coupling Reactions by Arkaitz Correa Pdf

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Author : Sylvia Munir Daoud Kinzie
Publisher : Unknown
Page : 252 pages
File Size : 43,9 Mb
Release : 2005
Category : Electronic
ISBN : UCLA:L0091033910

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Mutations Within the Second Coordination Sphere of Catalytic Iron (II) in Human Phenylalanine Hydroxylase (hPAH) that Affect the Environment and Electronic Geometry of Iron (II) are Implicated in Its Mechanism, Substrate Binding and Specificity by Sylvia Munir Daoud Kinzie Pdf