Modern Arylation Methods

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Modern Arylation Methods

Lutz Ackermann
Modern Arylation Methods Book PDF

Author : Lutz Ackermann
Publisher : John Wiley & Sons
Page : 561 pages
File Size : 55,7 Mb
Release : 2009-04-22
Category : Science
ISBN : 9783527627332

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Modern Arylation Methods by Lutz Ackermann Pdf

Today, arylation methods are belonging to the most important reaction types in organic synthesis. Lutz Ackermann, a young and ambitious professor has gathered a number of top international authors to present the first comprehensive book on the topic. Starting from a historical review, the book covers hot topics like Palladium-catalyzed arylation of N-H and alpha-C-H-acidic Bonds, Copper-catalyzed arylation of N-H and O-H Bonds, direct arylation reactions, carbanion aromatic synthesis, arylation reactions of alkenes, alkynes and much more. This compact source of high quality information is indispensable to synthetic chemists and those working in the pharmaceutical and chemical industry.

Catalytic Arylation Methods

Anthony J. Burke,Carolina Silva Marques
Catalytic Arylation Methods Book PDF

Author : Anthony J. Burke,Carolina Silva Marques
Publisher : John Wiley & Sons
Page : 530 pages
File Size : 42,9 Mb
Release : 2015-02-09
Category : Science
ISBN : 9783527335183

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Catalytic Arylation Methods by Anthony J. Burke,Carolina Silva Marques Pdf

This "hands-on" approach to the topic of arylation consolidates the body of key research over the last ten years (and up to around 2014) on various catalytic methods which involve an arylation process. Clearly structured, the chapters in this one-stop resource are arranged according to the reaction type, and focus on novel, efficient and sustainable processes, rather than the well-known and established cross-coupling methods. The entire contents are written by two authors with academic and industrial expertise to ensure consistent coverage of the latest developments in the field, as well as industrial applications, such as C-H activation, iron and gold-catalyzed coupling reactions, cycloadditions or novel methodologies using arylboron reagents. A cross-section of relevant tried-and-tested experimental protocols is included at the end of each chapter for putting into immediate practice, along with patent literature. Due to its emphasis on efficient, "green" methods and industrial applications of the products concerned, this interdisciplinary text will be essential reading for synthetic chemists in both academia and industry, especially in medicinal and process chemistry.

C-H Activation

Jin-Quan Yu,Zhangjie Shi
C H Activation Book PDF

Author : Jin-Quan Yu,Zhangjie Shi
Publisher : Springer
Page : 400 pages
File Size : 55,5 Mb
Release : 2010-06-16
Category : Science
ISBN : 9783642123566

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C-H Activation by Jin-Quan Yu,Zhangjie Shi Pdf

Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds - Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C–H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation - Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages - Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds - Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C–H to C–N Bonds

Modern Aryne Chemistry

Akkattu T. Biju
Modern Aryne Chemistry Book PDF

Author : Akkattu T. Biju
Publisher : John Wiley & Sons
Page : 530 pages
File Size : 55,6 Mb
Release : 2021-08-23
Category : Science
ISBN : 9783527346462

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Modern Aryne Chemistry by Akkattu T. Biju Pdf

A groundbreaking book to offer a a comprehensive account of important reactions involving arynes Modern Aryne Chemistry is the first book on the market to offer a conceptual framework to the reactions related to arynes. It also provides a systematic introduction to the cycloaddition reactions, insertion reactions and transition-metal-catalyzed transformations of arynes. The author, a noted expert on the topic, highlights a novel strategy for carbon-carbon and carbon-heteroatom bond construction using arynes. The book reveiws the recent use of aryne chemistry for the development of new multicomponent reactions. New advances in this area has shown rapid emergence of a new class of reactions classified under rearrangement reactions. The author also includes information on aryne methods that have been employed for the synthesis of several natural products. The simplicity and sophistication of the synthetic strategy using arynes can serve as a springboard for organic chemists to explore new possibilities and imagine applications of the concept of arynes. This important book: Presents a one-of-kind comprehensive guide to arynes reactions Offers a proven approach to the synthesis of natural product and polymers Reviews the most recent developments in the carbon-carbon and carbon-heteroatom bond-forming reactions involving arynes Written for organic, pharmaceutical, medicinal, natural products, and catalytic Chemists, Modern Aryne Chemistry offers a comprehensive review of the fundamentals of reactions related to arynes and the most recent developments in the field.

Synthetic Methods in Drug Discovery

David C Blakemore,Paul M Doyle,Yvette M Fobian
Synthetic Methods in Drug Discovery Book PDF

Author : David C Blakemore,Paul M Doyle,Yvette M Fobian
Publisher : Royal Society of Chemistry
Page : 455 pages
File Size : 46,8 Mb
Release : 2016-07-15
Category : Science
ISBN : 9781782622086

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Synthetic Methods in Drug Discovery by David C Blakemore,Paul M Doyle,Yvette M Fobian Pdf

Synthetic Methods in Drug Discovery Volume 1 focusses on the hugely important area of transition metal mediated methods used in industry. Current methods of importance such as the Suzuki-Miyaura coupling, Buchwald-Hartwig couplings and CH activation are discussed. In addition, exciting emerging areas such as decarboxylative coupling, and the uses of iron and nickel in coupling reactions are also covered. This book provides both academic and industrial perspectives on some key reactions giving the reader an excellent overview of the techniques used in modern synthesis. Reaction types are conveniently framed in the context of their value to industry and the challenges and limitations of methodologies are discussed with relevant illustrative examples. Edited and authored by leading scientists from both academia and industry, this book will be a valuable reference for all chemists involved in drug discovery as well as postgraduate students in medicinal chemistry.

Green Synthetic Approaches for Biologically Relevant Heterocycles

Goutam Brahmachari
Green Synthetic Approaches for Biologically Relevant Heterocycles Book PDF

Author : Goutam Brahmachari
Publisher : Elsevier
Page : 646 pages
File Size : 52,6 Mb
Release : 2021-03-20
Category : Science
ISBN : 9780323851305

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Green Synthetic Approaches for Biologically Relevant Heterocycles by Goutam Brahmachari Pdf

Green Synthetic Approaches for Biologically Relevant Heterocycles, Second Edition, Volume One: Advanced Synthetic Techniques reviews this significant group of organic compounds within the context of sustainable methods and processes, expanding on the first edition with fully updated coverage and a whole range of new chapters. Volume One explores advanced synthetic techniques, with each chapter presenting in-depth coverage of various green protocols for the synthesis of a wide variety of bioactive heterocycles that are classified on the basis of ring-size and/or the presence of heteroatoms. Techniques covered range from high pressure cycloaddition reactions and microwave irradiation to sustainable one-pot domino reactions. This updated edition is an essential resource on sustainable approaches for academic researchers, R&D professionals, and students working across medicinal, organic, natural product and green chemistry. Provides fully updated coverage of the field of greener heterocycle synthesis Includes new chapters on varied multicomponent reactions, alongside both traditional and novel approaches Presents information in an accessible style with an emphasis on sustainability

Organometallic Chemistry

Ian J. S. Fairlamb,Jason M. Lynam
Organometallic Chemistry Book PDF

Author : Ian J. S. Fairlamb,Jason M. Lynam
Publisher : Royal Society of Chemistry
Page : 186 pages
File Size : 43,8 Mb
Release : 2012-06
Category : Reference
ISBN : 9781849733762

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Organometallic Chemistry by Ian J. S. Fairlamb,Jason M. Lynam Pdf

A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M3ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields.

Esterification

Junzo Otera,Joji Nishikido
Esterification Book PDF

Author : Junzo Otera,Joji Nishikido
Publisher : John Wiley & Sons
Page : 386 pages
File Size : 45,5 Mb
Release : 2009-11-10
Category : Science
ISBN : 3527627634

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Esterification by Junzo Otera,Joji Nishikido Pdf

Gathering together the widespread literature in the field, this monograph acts as a reference guide to this very important chemical reaction. Following an introduction, the book goes on to discuss methodology, before treating synthetic and industrial applications -- the latter being a new focus in this completely revised, updated and extended second edition. A must-have for organic, natural products and catalytic chemists, as well as those working in industry, of for lecturers in chemistry.

Heterocycles via Cross Dehydrogenative Coupling

Ananya Srivastava,Chandan K. Jana
Heterocycles via Cross Dehydrogenative Coupling Book PDF

Author : Ananya Srivastava,Chandan K. Jana
Publisher : Springer Nature
Page : 494 pages
File Size : 44,5 Mb
Release : 2019-08-23
Category : Science
ISBN : 9789811391446

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Heterocycles via Cross Dehydrogenative Coupling by Ananya Srivastava,Chandan K. Jana Pdf

This book discusses the developments in the synthesis and functionalization of different heterocycles based on the formation of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds using cross-dehydrogenative coupling (CDC). Consisting of 13 chapters, the book systematically describes the advances in the synthesis and functionalization of nitrogen, oxygen, and sulfur-containing heterocycles. It also discusses the various mechanistic pathways to help readers gain an in-depth understanding of the CDC reactions of heterocycles. Lastly, in order to promote green chemistry, it addresses a range of metal-free CDC reactions of heterocycles – an area that has attracted significant attention in both academic and industrial research.

Green Processes

Anonim
Green Processes Book PDF

Author : Anonim
Publisher : John Wiley & Sons
Page : 446 pages
File Size : 49,9 Mb
Release : 2014-04-22
Category : Science
ISBN : 9783527688494

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Green Processes by Anonim Pdf

Edited by Professor CJ Li, one of the leading international experts in the fields of Green Chemistry and Green Synthesis, this volume presents such hot topics as synthesis without protecting groups, multi-component reactions, and synthesis in green solvents. The Handbook of Green Chemistry comprises of 9 volumes in total, split into 3 subject-specific sets. The three sets are available individually. All 9 volumes are available individually, too. Set I: Green Catalysis - Volume 1: Homogeneous Catalysis - Volume 2: Heterogeneous Catalysis - Volume 3: Biocatalysis Set II: Green Solvents - Volume 4: Supercritical Solvents - Volume 5: Reactions in Water - Volume 6: Ionic Liquids Set III: Green Processes - Volume 7: Green Synthesis - Volume 8: Green Nanoscience - Volume 9: Designing Safer Chemicals The Handbook of Green Chemistry is also available as Online Edition. Podcasts Listen to two podcasts in which Professor Paul Anastas and Journals Editor Paul Trevorrow discuss the origin and expansion of Green Chemistry and give an overview of The Handbook of Green Chemistry.

Radicals in Synthesis III

Markus Heinrich,Andreas Gansäuer
Radicals in Synthesis III Book PDF

Author : Markus Heinrich,Andreas Gansäuer
Publisher : Springer Science & Business Media
Page : 465 pages
File Size : 49,9 Mb
Release : 2012-02-22
Category : Science
ISBN : 9783642281228

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Radicals in Synthesis III by Markus Heinrich,Andreas Gansäuer Pdf

Boron-Doped Diamond Electrodes for Electroorganic Chemistry, by Siegfried R. Waldvogel, Stamo Mentizi und Axel Kirste.- Modern Developments in Aryl Radical Chemistry, by Gerald Pratsch und Markus R. Heinrich.- Radical Additions to Chiral Hydrazones: Stereoselectivity and Functional Group Compatibility, by Gregory K. Friestad.- Hydrogen Atom Donors: Recent Developments, by Andreas Gansäuer, Lei Shi, Matthias Otte, Inga Huth, Antonio Rosales, Iris Sancho-Sanz, Natalia M. Padial und J. Enrique Oltra.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? - A Fruitful Interplay Anyway Part 1. Radical Catalysis by Group 4 to Group 7 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? - A Fruitful Interplay Anyway Part 2. Radical Catalysis by Group 8 and 9 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway Part 3: Catalysis by Group 10 and 11 Elements and Bimetallic Catalysis, by Ullrich Jahn.-

Applied Cross-Coupling Reactions

Yasushi Nishihara
Applied Cross Coupling Reactions Book PDF

Author : Yasushi Nishihara
Publisher : Springer Science & Business Media
Page : 245 pages
File Size : 53,9 Mb
Release : 2012-12-14
Category : Science
ISBN : 9783642323683

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Applied Cross-Coupling Reactions by Yasushi Nishihara Pdf

“Applied Cross-Coupling Reactions” provides students and teachers of advanced organic chemistry with an overview of the history, mechanisms and applications of cross-coupling reactions. Since the discovery of the transition-metal-catalyzed cross-coupling reactions in 1972, numerous synthetic uses and industrial applications have been developed. The mechanistic studies of the cross-coupling reactions have disclosed that three fundamental reactions: oxidative addition, transmetalation, and reductive elimination, are involved in a catalytic cycle. Cross-coupling reactions have allowed us to produce a variety of compounds for industrial purposes, such as natural products, pharmaceuticals, liquid crystals and conjugate polymers for use in electronic devices. Indeed, the Nobel Prize for Chemistry in 2010 was awarded for work on cross-coupling reactions. In this book, the recent trends in cross-coupling reactions are also introduced from the point of view of synthesis design and catalytic activities of transition-metal catalysts.

Chemistry Beyond Chlorine

Pietro Tundo,Liang-Nian He,Ekaterina Lokteva,Claudio Mota
Chemistry Beyond Chlorine Book PDF

Author : Pietro Tundo,Liang-Nian He,Ekaterina Lokteva,Claudio Mota
Publisher : Springer
Page : 608 pages
File Size : 44,7 Mb
Release : 2016-09-17
Category : Science
ISBN : 9783319300733

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Chemistry Beyond Chlorine by Pietro Tundo,Liang-Nian He,Ekaterina Lokteva,Claudio Mota Pdf

Since the industrial revolution, chlorine remains an iconic molecule even though its production by the electrolysis of sodium chloride is extremely energy intensive. The rationale behind this book is to present useful and industrially relevant examples for alternatives to chlorine in synthesis. This multi-authored volume presents numerous contributions from an international spectrum of authors that demonstrate how to facilitate the development of industrially relevant and implementable breakthrough technologies. This volume will interest individuals working in organic synthesis in industry and academia who are working in Green Chemistry and Sustainable Technologies.

C-H Bond Activation and Catalytic Functionalization I

Pierre H. Dixneuf,Henri Doucet
C H Bond Activation and Catalytic Functionalization I Book PDF

Author : Pierre H. Dixneuf,Henri Doucet
Publisher : Springer
Page : 264 pages
File Size : 43,5 Mb
Release : 2015-12-18
Category : Science
ISBN : 9783319246307

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C-H Bond Activation and Catalytic Functionalization I by Pierre H. Dixneuf,Henri Doucet Pdf

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Metal Catalyzed Cross-Coupling Reactions and More

Armin de Meijere,Stefan Bräse,Martin Oestreich
Metal Catalyzed Cross Coupling Reactions and More Book PDF

Author : Armin de Meijere,Stefan Bräse,Martin Oestreich
Publisher : John Wiley & Sons
Page : 1640 pages
File Size : 44,9 Mb
Release : 2013-12-04
Category : Science
ISBN : 9783527655601

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Metal Catalyzed Cross-Coupling Reactions and More by Armin de Meijere,Stefan Bräse,Martin Oestreich Pdf

This three volume book is the follow-up handbook to the bestselling volume "Metal-Catalyzed Cross-Coupling Reactions", the definitive reference in the field. In line with the enormous developments in this area, this is not a new edition, but rather a new book in three volumes with over 50% more content. This new content includes C-H activation, shifting the focus away from typical cross-coupling reactions, while those topics and chapters found in de Meijere/Diederich's book have been updated and expanded. With its highly experienced editor team and the list of authors reading like an international Who's-Who in the field, this work will be of great interest to every synthetic chemist working in academia and industry.