Principles And Applications Of Stereochemistry

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Principles and Applications of Stereochemistry

Michael North
Principles and Applications of Stereochemistry Book PDF

Author : Michael North
Publisher : Routledge
Page : 269 pages
File Size : 45,9 Mb
Release : 2017-10-19
Category : Medical
ISBN : 9781351422055

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Principles and Applications of Stereochemistry by Michael North Pdf

A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.

Stereochemistry of Organic Compounds

D. Nasipuri
Stereochemistry of Organic Compounds Book PDF

Author : D. Nasipuri
Publisher : John Wiley & Sons
Page : 554 pages
File Size : 48,7 Mb
Release : 1991
Category : Science
ISBN : UOM:39015038998087

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Stereochemistry of Organic Compounds by D. Nasipuri Pdf

This text deals with the new concepts and terminology that have been introduced into the treatment of organic stereochemistry over the last decade. Organic reaction mechanisms, as they relate to stereochemistry, are included, and the pericyclic reaction using the frontier molecular orbital approach is explained. The text does not assume a strong grounding in organic chemistry and will therefore be useful to a broader spectrum of students - both graduate and undergraduate. The volume features numerous illustrations and programmed problems.

Dynamic Stereochemistry of Chiral Compounds

Christian Wolf
Dynamic Stereochemistry of Chiral Compounds Book PDF

Author : Christian Wolf
Publisher : Royal Society of Chemistry
Page : 534 pages
File Size : 46,9 Mb
Release : 2008
Category : Education
ISBN : 9780854042463

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Dynamic Stereochemistry of Chiral Compounds by Christian Wolf Pdf

A comprehensive overview of fundamental concepts of asymmetric synthesis along with in-depth discussion. Recent developments that address important synthetic challenges are presented and highlighted with hundreds of examples.

Stereochemistry of Organic Compounds

D. Nasipuri
Stereochemistry of Organic Compounds Book PDF

Author : D. Nasipuri
Publisher : New Age International
Page : 596 pages
File Size : 51,7 Mb
Release : 1994
Category : Science
ISBN : 8122405703

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Stereochemistry of Organic Compounds by D. Nasipuri Pdf

During Recent Years, Stereochemistry Has Undergone A Phenomenal Growth Both In Theory And Practice, With A Concomitant Increase Of Interest Among The Organic Chemists, Biological Chemists, Medicinal Chemists, And Pharmacologists. The Present Text Provides An Up-To-Date, Coherent; And Comprehensive Account Of The Subject Starting From The Fundamentals And Leading Up To The Latest Development As Far As Practicable. Emphasis Has Been Placed On Symmetry-Based Approach To Molecular Chirality, Stereochemical Terminologies (Modern Stereochemistry Is Replete, With Them), Topicity And Prostereoisomerism, Conformational Analysis, Dynamic Stereochemistry, Chiroptical Properties, And Assignment Of Absolute Configuration To Chiral Molecules.Dynamic Stereochemistry Has Been Discussed With Reference To Conformation-Reactivity Correlation, Stereoselective Syntheses, And Pericyclic Reactions. A Large Cross Section Of Organic Reactions With Stereochemical Implication Has Been Incorporated. Attempts Have Been Made To Familiarise The Readers With Modem Instrumental Techniques, Nuclear Magnetic Resonance In Particular, Used For Stereochemical Investigation. Each Chapter Is Provided With A Summary Which Highlights The Main Points Of The Text. Selective References, Mostly Of Textbooks, Monographs, Review Articles, And Significant Original Papers Have Been Given Extending Sometimes To Early 1991.The Book Is Expected To Fulfil The Long-Felt Need For A Comprehensive Text On Modern Organic Stereochemistry Which Is Conspicuously Absent Since The Publication Of Professor Eliels Book In 1962. The Text May Be Adopted At Any Stage Of The University Teaching And At The Same Time Be Useful To The Practising Organic Chemists.

Stereochemistry

Anil V. Karnik,Mohammed Hasan
Stereochemistry Book PDF

Author : Anil V. Karnik,Mohammed Hasan
Publisher : Elsevier
Page : 622 pages
File Size : 54,5 Mb
Release : 2021-07-21
Category : Science
ISBN : 9780128210635

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Stereochemistry by Anil V. Karnik,Mohammed Hasan Pdf

Stereochemistry: A Three-Dimensional Insight draws on the knowledge of its expert authors, providing a systematic treatment on the fundamental aspects of stereochemistry, covering conformational aspects, configurational aspects, effects of bulkiness, stereoelectronic effects on properties of molecules, and the genesis of enantiomerism, among other topics. Visuals and exercises are included to consolidate the principles learned, and the contents are carefully structured to prepare readers for predicting and organizing reaction components to obtain desired stereochemical outcomes. This book is an indispensable guide for all those exploring stereochemistry within their work. The principles of stereochemistry are fundamental to understanding chemical behavior and can provide insights into a whole range of problems, from unusual selectivity and unexpected behaviors, to abnormally fast reactions and surprising biochemical preferences. However, understanding and exploring these 3D effects can be difficult within a 2D medium. This book has been designed to address this problem, providing foundational guidance on the principles and applications of stereochemistry that are fully supported by multimedia visuals. Combines foundational concepts and definitions with examples of stereochemistry in practice Highlights the conformational and configurational impact of atomic arrangement on chemical behavior Outlines methods of analysis Provides practical exercises and detailed multimedia visuals to support learning

Stereochemistry

M. Nógrádi
Stereochemistry Book PDF

Author : M. Nógrádi
Publisher : Elsevier
Page : 300 pages
File Size : 41,6 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483278650

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Stereochemistry by M. Nógrádi Pdf

Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.

Organic Stereochemistry

Hua-Jie Zhu
Organic Stereochemistry Book PDF

Author : Hua-Jie Zhu
Publisher : John Wiley & Sons
Page : 336 pages
File Size : 50,8 Mb
Release : 2015-08-10
Category : Science
ISBN : 9783527338221

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Organic Stereochemistry by Hua-Jie Zhu Pdf

Adopting a novel approach to the topic by combining theoretical knowledge and practical results, this book presents the most popular and useful computational and experimental methods applied for studying the stereochemistry of chemical reactions and compounds. The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book. A valuable reference for researchers in academia and industry working in the field of organic synthesis, computational chemistry, spectroscopy or medicinal chemistry.

Principles of Organic Chemistry

Robert J. Ouellette,J. David Rawn
Principles of Organic Chemistry Book PDF

Author : Robert J. Ouellette,J. David Rawn
Publisher : Academic Press
Page : 496 pages
File Size : 41,9 Mb
Release : 2015-02-13
Category : Science
ISBN : 9780128026342

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Principles of Organic Chemistry by Robert J. Ouellette,J. David Rawn Pdf

Class-tested and thoughtfully designed for student engagement, Principles of Organic Chemistry provides the tools and foundations needed by students in a short course or one-semester class on the subject. This book does not dilute the material or rely on rote memorization. Rather, it focuses on the underlying principles in order to make accessible the science that underpins so much of our day-to-day lives, as well as present further study and practice in medical and scientific fields. This book provides context and structure for learning the fundamental principles of organic chemistry, enabling the reader to proceed from simple to complex examples in a systematic and logical way. Utilizing clear and consistently colored figures, Principles of Organic Chemistry begins by exploring the step-by-step processes (or mechanisms) by which reactions occur to create molecular structures. It then describes some of the many ways these reactions make new compounds, examined by functional groups and corresponding common reaction mechanisms. Throughout, this book includes biochemical and pharmaceutical examples with varying degrees of difficulty, with worked answers and without, as well as advanced topics in later chapters for optional coverage. Incorporates valuable and engaging applications of the content to biological and industrial uses Includes a wealth of useful figures and problems to support reader comprehension and study Provides a high quality chapter on stereochemistry as well as advanced topics such as synthetic polymers and spectroscopy for class customization

NMR of Paramagnetic Molecules

G. N. La Mar,W. Dew. Horrocks,R. H. Holm
NMR of Paramagnetic Molecules Book PDF

Author : G. N. La Mar,W. Dew. Horrocks,R. H. Holm
Publisher : Elsevier
Page : 695 pages
File Size : 44,7 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483272450

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NMR of Paramagnetic Molecules by G. N. La Mar,W. Dew. Horrocks,R. H. Holm Pdf

NMR of Paramagnetic Molecules: Principles and Applications is a compendium of papers that discusses the physical principles behind the technique of nuclear magnetic resonance, as well as, evaluates the scope and limitation of the applications of NMR in chemistry and biology. These papers emphasize the applications of the technique in chemistry and biochemistry where it widely used, particularlyon NMR experiments in the liquid state. Some papers describe the theoretical factors governing the resonance position and linewidth, and then also interpret magnetic resonance parameters in terms of electronic structure. Another paper investigates the gap between the mathematical complexities of earlier experiments and the operational aspects of chemical information from the spectra. Examples show studies in biochemical molecules and process in events where contact interactions are present either as a result of intrinsic molecular paramagnetism or are just induced through the addition of suitable paramagnetic probes. One paper presents the definitive and controversial results involving stereochemistry and deuterium NMR. This collection of papers will prove useful for nuclear physicists, researchers, and academicians in the field of nuclear physics.

Taste Chemistry

R.S. Shallenberger
Taste Chemistry Book PDF

Author : R.S. Shallenberger
Publisher : Springer Science & Business Media
Page : 633 pages
File Size : 40,8 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9781461526667

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Taste Chemistry by R.S. Shallenberger Pdf

The object ofthis text is to examine, and elaborate on the meaning of the established premise that 'taste is a chemical sense.' In particular, the major effort is directed toward the degree to which chemical principles apply to phenomena associated with the inductive (recognition) phase of taste. A second objective is to describe the structure and properties of compounds with varying taste that allow decisions to be made with respect to the probable nature of the recognition chemistry for the different tastes, and the probable nature of the receptor(s) for those tastes. A final objective is to include appropriate interdisciplinary observations that have application to solving problems related to the chemical nature of taste. Taste is the most easily accessible chemical structure-biological activity relationship, and taste chemistry studies, i.e. the chemistry of sweetness, saltiness, sourness, and bitterness, have application to general biology, physiology, and pharmacology. Because it involves sensory perception, taste is also of interest to psychologists, and has application to the food and agricultural industries. The largest portion of the text is directed toward sweetness as, due to economic and other factors, the majority of the scientific studies are concerned with sweetness. The text begins with a prologue to describe the problems associated with the study of taste chemistry. Then, there is an introductory chapter to serve as an overview of the general interdisciplinary knowledge of the subject. It is followed by a chapter on the fundamental chemical principles that apply to taste induction chemistry.

Rules for the Nomenclature of Organic Chemistry

L. C. Cross,W. Klyne
Rules for the Nomenclature of Organic Chemistry Book PDF

Author : L. C. Cross,W. Klyne
Publisher : Elsevier
Page : 21 pages
File Size : 49,9 Mb
Release : 2013-09-17
Category : Science
ISBN : 9781483284507

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Rules for the Nomenclature of Organic Chemistry by L. C. Cross,W. Klyne Pdf

Rules for the Nomenclature of Organic Chemistry: Section E: Stereochemistry (Recommendations 1974) deals with the main principles of stereochemistry. The rules discussed in this section have two main objects, namely, to prescribe, for basic views, terms that may provide a common language in all aspects of stereochemistry; and to define the ways in which these terms may be incorporated into the names of individual compounds. This book discusses the steric structure of a compound, which is denoted by an affix or affixes to the name that does not prescribe the stereochemistry. This text explains that isomers are termed stereoisomers when they differ only in the arrangement of the atoms in space. This book explains as well that the terms relative stereochemistry and relative configuration are used to describe the positions of substituents on different atoms in a molecule relative to one another. This book is a valuable resource for organic chemists.

Ord and Cd in Chemistry and Biochemistry

Pierre Crabbe
Ord and Cd in Chemistry and Biochemistry Book PDF

Author : Pierre Crabbe
Publisher : Elsevier
Page : 241 pages
File Size : 49,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323159418

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Ord and Cd in Chemistry and Biochemistry by Pierre Crabbe Pdf

ORD and CD in Chemistry and Biochemistry: An Introduction essentially presents the necessary foreword and theoretical foundation for the useful application of optical rotatory dispersion (ORD) and circular dichroism (CD) to certain common chemical problems. This book emphasizes the precision of ORD and CD data in terms of stereochemical information. The book begins with some historical references and a concise review of basic principles on stereochemistry. It further delves onto the phenomena of optical activity. Also included are the definitions and units commonly used in ORD and CD. The book also discusses optical properties of polymers, organometallic, and inorganic derivatives; and some of the aspects of magnetic optical rotator dispersion (MORD) and magnetic circular dichroism (MCD). A table that presents wavelength range of the Cotton effects of most chromophoric groupings concludes the book. This monograph is a helpful reference to students as well as professionals from both chemistry and biochemistry fields of science.

Stereochemistry of Coordination Compounds

Alexander von Zelewsky
Stereochemistry of Coordination Compounds Book PDF

Author : Alexander von Zelewsky
Publisher : John Wiley & Sons
Page : 272 pages
File Size : 42,7 Mb
Release : 1996-06-03
Category : Science
ISBN : 047195599X

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Stereochemistry of Coordination Compounds by Alexander von Zelewsky Pdf

This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.

Organic Chemistry

Robert J. Ouellette,J. David Rawn
Organic Chemistry Book PDF

Author : Robert J. Ouellette,J. David Rawn
Publisher : Elsevier
Page : 1240 pages
File Size : 42,8 Mb
Release : 2014-06-06
Category : Science
ISBN : 9780128010822

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Organic Chemistry by Robert J. Ouellette,J. David Rawn Pdf

Organic Chemistry provides a comprehensive discussion of the basic principles of organic chemistry in their relation to a host of other fields in both physical and biological sciences. This book is written based on the premise that there are no shortcuts in organic chemistry, and that understanding and mastery cannot be achieved without devoting adequate time and attention to the theories and concepts of the discipline. It lays emphasis on connecting the basic principles of organic chemistry to real world challenges that require analysis, not just recall. This text covers topics ranging from structure and bonding in organic compounds to functional groups and their properties; identification of functional groups by infrared spectroscopy; organic reaction mechanisms; structures and reactions of alkanes and cycloalkanes; nucleophilic substitution and elimination reactions; conjugated alkenes and allylic systems; electrophilic aromatic substitution; carboxylic acids; and synthetic polymers. Throughout the book, principles logically evolve from one to the next, from the simplest to the most complex examples, with abundant connections between the text and real world applications. There are extensive examples of biological relevance, along with a chapter on organometallic chemistry not found in other standard references. This book will be of interest to chemists, life scientists, food scientists, pharmacists, and students in the physical and life sciences. Contains extensive examples of biological relevance Includes an important chapter on organometallic chemistry not found in other standard references Extended, illustrated glossary Appendices on thermodynamics, kinetics, and transition state theory

Circular Dichroism

Nina Berova,Koji Nakanishi,Robert W. Woody
Circular Dichroism Book PDF

Author : Nina Berova,Koji Nakanishi,Robert W. Woody
Publisher : John Wiley & Sons
Page : 916 pages
File Size : 53,6 Mb
Release : 2000-05-03
Category : Science
ISBN : 0471330035

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Circular Dichroism by Nina Berova,Koji Nakanishi,Robert W. Woody Pdf

Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Moleküle. CD-Effekte lassen sich in Abhängigkeit von der Wellenlänge messen und spektroskopisch auswerten. Dieser Band erläutert Theorie und Anwendung der CD-Spektroskopie insbesondere für Biomoleküle. Ausführlich behandelt werden Anwendungen auf den Gebieten der organischen Stereochemie und der Biopolymere. Geschrieben von anerkannten Spezialisten! (06/00)