The Organic Chemistry Of Boron

Author : Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes
Publisher : Royal Society of Chemistry
Page : 555 pages
File Size : 44,9 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847550644

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Contemporary Boron Chemistry by Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes Pdf

The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.

Author : William Gerrard
Publisher : Unknown
Page : 328 pages
File Size : 45,5 Mb
Release : 1961
Category : Science
ISBN : UCAL:B4050287

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The Organic Chemistry of Boron by William Gerrard Pdf

Author : E. Fernández
Publisher : Thieme
Page : 582 pages
File Size : 55,9 Mb
Release : 2020-05-22
Category : Science
ISBN : 9783132429734

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Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis by E. Fernández Pdf

The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.

Author : Adiel Coca
Publisher : ACS Symposium
Page : 544 pages
File Size : 51,9 Mb
Release : 2018-02-02
Category : Science
ISBN : 0841231834

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Boron Reagents in Synthesis by Adiel Coca Pdf

Boron compounds have been used extensively in organic synthesis for more than sixty years. Some of the best known reactions in synthesis, such as the Suzuki-Miyaura cross-coupling and the hydroboration reaction, involve boron compounds. Several natural products containing boron have been isolated in the last fifty years, including ionophoric macrodiolide antibiotics boromycin, borophycin, aplasmomycins A, B, and C, and tartrolons B, C, and E, as well as autoinducer-2. The study of compounds containing boronic acids for application in pharmaceuticals and materials science has grown tremendously over the last few decades. These include bortezomib, ixazomib, and tavaborole. Several more boron-based drugs are currently in clinical trials. Boron neutron capture therapy has the potential to provide a treatment for various cancers. In addition, materials bearing boronic acids are been studied as potential sensors for biological molecules, such as saccharides and glycoproteins that possess cis-1,2- or cis-1,3-diols.

Author : Anonim
Publisher : Georg Thieme Verlag
Page : 986 pages
File Size : 49,8 Mb
Release : 2014-05-14
Category : Science
ISBN : 9783131806949

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Houben-Weyl Methods of Organic Chemistry Vol. XIII/3c, 4th Edition by Anonim Pdf

Houben-Weyl is the acclaimed reference series for preparative methods in organic chemistry, in which all methods are organized accor ding to the class of compound or functional group to be synthesized. The Houben-Weyl volumes contain 146 000 product-specific experi mental procedures, 580 000 structures, and 700 000 references. The preparative significance of the methods for all classes of compou nds is critically evaluated. The series includes data from as far back as the early 1800s to 2003. // The content of this e-book was originally published in 1984.

Author : Susan E. Thomas
Publisher : Unknown
Page : 128 pages
File Size : 40,5 Mb
Release : 1991
Category : Electronic
ISBN : OCLC:474244122

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Organic Synthesis, the Roles of Boron and Silicon by Susan E. Thomas Pdf

Author : A. V. Topchiev,S. V. Zavgorodnii,Ya. M. Paushkin
Publisher : Elsevier
Page : 327 pages
File Size : 40,9 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483184364

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Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry by A. V. Topchiev,S. V. Zavgorodnii,Ya. M. Paushkin Pdf

Boron Fluoride and Its Compounds as Catalysts in Organic Chemistry deals with the concerns associated with the utilization of boron fluoride as a catalyst. The title provides a comprehensive account of boron fluoride, such as its properties, compounds, and related methodologies. The coverage of the text includes the preparation and recovery of boron fluoride, along with the physical and chemical properties. The selection also covers various boron fluoride compounds and their respective reaction to various processes, such as alkylation, polymerization, and nitration. The book will be of great interest to students, researchers, and practitioners of organic chemistry.

Author : Elena Fernández,Andrew Whiting
Publisher : Springer
Page : 331 pages
File Size : 42,5 Mb
Release : 2015-03-04
Category : Science
ISBN : 9783319130545

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Synthesis and Application of Organoboron Compounds by Elena Fernández,Andrew Whiting Pdf

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Author : Hijazi Abu Ali,Valery M Dembitsky,Morris Srebnik
Publisher : Elsevier
Page : 631 pages
File Size : 43,6 Mb
Release : 2005-09-07
Category : Science
ISBN : 9780080457734

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Contemporary Aspects of Boron: Chemistry and Biological Applications by Hijazi Abu Ali,Valery M Dembitsky,Morris Srebnik Pdf

Contemporary Aspects of Boron: Chemistry and Biological Applications highlights the biological activity and applications of boron containing compounds. The authors’ specific approach surveys general features of the subject, while exploring new and novel strategies for preparing certain chemical and natural boron products that are of significant substance in medicinal chemistry. For example, cancer treatment is one of the most important issues related to such products. In addition to contributing to the development of new drugs by addressing biological applications in medicinal and industrial fields, the book provides a comprehensive review of the most relevant components that comprise the pharmaceutical, medicinal and environmental applications of boron containing compounds. * Timely and comprehensive * Provides new insights to active researchers in the field * Presents concepts and methods in simple scientific terms

Author : Anonim
Publisher : John Wiley & Sons
Page : 4 pages
File Size : 46,5 Mb
Release : 2021-10-25
Category : Science
ISBN : 9781119518044

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The Chemistry of Organoboron Compounds, 2 Volume Set by Anonim Pdf

The ultimate resource in organoboron chemistry Professor Mark Gandelman and his colleagues delve deeply into the theory, structure, analysis, synthesis, and reactions of organoboron chemistry in The Chemistry of Organoboron Compounds. Organoborons are used heavily as highly efficient reagents in many reactions, including cross-coupling and radical reactions. The highly regarded authors have tied together organic-chemical and physico-chemical knowledge usually unavailable from a single source. The book focuses on the use of completely biodegradable "green" reagents, as opposed to environmentally hazardous heavy metal catalysts. The Chemistry of Organoboron Compounds delivers comprehensive and complete information on: The behavior of organoboron compounds The use of organoboron compounds in organic synthesis The commercial applications of organoboron compounds As a volume in the celebrated Patai book series, The Chemistry of Organoboron Compounds includes all the features that readers of that series are used to enjoying, including a comprehensive index at the back of the book.

Author : Herbert C. Brown
Publisher : Cornell University Press
Page : 488 pages
File Size : 43,5 Mb
Release : 2019-06-30
Category : Science
ISBN : 9781501741432

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Boranes in Organic Chemistry by Herbert C. Brown Pdf

The leading researcher in the uses of boranes in organic synthesis here reviews his work over the past thirty-five years, covering such areas as steric strains, the nonclassical ion problem, selective reductions, hydroboration, and the organoboranes as synthetic intermediates. But more than an exposition of enormous accomplishment, the book is a scientific autobiography that will provide chemists with historical perspective on their profession. The author's detailed narrative of his own research experiences not only adds to the understanding of the present state of the study of boranes, but will serve as a stimulus to imaginative research in the future.

Author : Yinghuai Zhu
Publisher : Elsevier
Page : 431 pages
File Size : 55,6 Mb
Release : 2022-03-17
Category : Science
ISBN : 9780128221266

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Fundamentals and Applications of Boron Chemistry by Yinghuai Zhu Pdf

Fundamentals and Applications of Boron Chemistry highlights its impressive potential for current and future developments across a range of fields, providing foundational information on boron chemistry and systematically summarizing applications of boron in energy, medicinal chemistry, and materials chemistry. Beginning with an introduction to boron chemistry which outlines the boron element and its physical and chemical properties, this book goes on to discuss advances in boron coordination chemistry, before delving deeper into key fields of application. The latest developments in boron-based catalysts in organic reactions are reviewed, followed by novel emerging boron-containing materials and their potential applications in areas such as hydrogen storage, and boron materials with special optical activity. Finally, advance boron-based drugs and therapies are explored. This book fills the current market gap, systematically summarizing developments and applications of boron in energy, medicinal chemistry, and materials chemistry in a single, accessible volume. It is a valuable reference for chemists, students, and researchers in relative areas. Outlines the foundational principles and properties of boron chemistry Highlights developments in the application of boron chemistry across key areas, including catalysis, sustainable energy, material development, and pharmaceuticals Using active words to start them off Inspires researchers in developing future applications based on boron’s chemical characteristics and activity

Author : Gordon M. L. Cragg
Publisher : Unknown
Page : 448 pages
File Size : 41,9 Mb
Release : 1973
Category : Science
ISBN : UOM:39015016063615

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Organoboranes in Organic Synthesis by Gordon M. L. Cragg Pdf

Author : Heinrich Nöth,Bernd Wrackmeyer
Publisher : Springer Science & Business Media
Page : 474 pages
File Size : 45,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642667572

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Nuclear Magnetic Resonance Spectroscopy of Boron Compounds by Heinrich Nöth,Bernd Wrackmeyer Pdf

The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes, carboranes, metalloboranes, etc. , and although certain patterns have emerged, the correlation between the observed chemical shift and the assigned structural unit is still not fully understood. Therefore, predictions in this area are still rather limited, and semiquantitative interpretations are not yet pos sible. Several years ago Eaton and Lipscomb sUpImarized the status in this field in their book "NMR Studies of Boron Hydrides and Related Compounds" and a plethora of new data has accumulated since then. The book also contained material on simple bo rane derivatives, but they were not discussed in any detail. On the other hand many systematic studies, both synthetic and spectroscopic, have been conducted on these simple boron materials in the last decade. Thus a large amount of NMR information is available, not only on lIB but also on 1 H, 1 3 C, and 14 N. However, this information is widely scattered in the literature, and often the data are not discussed at all. It see med appropriate, therefore, to collect these data and to present them in one volume.

Author : Dennis G. Hall,Hugo Lachance
Publisher : John Wiley & Sons
Page : 6 pages
File Size : 53,9 Mb
Release : 2012-05-29
Category : Science
ISBN : 9781118344453

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Organic Reactions, Volume 73 by Dennis G. Hall,Hugo Lachance Pdf

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.