Topics In Inorganic And Organometallic Stereochemistry

Author : Gregory L. Geoffroy
Publisher : John Wiley & Sons
Page : 366 pages
File Size : 43,7 Mb
Release : 2009-09-17
Category : Science
ISBN : 9780470147436

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Topics in Inorganic and Organometallic Stereochemistry by Gregory L. Geoffroy Pdf

This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.

Author : Anonim
Publisher : Unknown
Page : 352 pages
File Size : 51,5 Mb
Release : 1981
Category : Electronic
ISBN : OCLC:867206412

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Topics in Stereochemistry. by Anonim Pdf

Author : Robert B. Jordan
Publisher : Oxford University Press
Page : 532 pages
File Size : 42,8 Mb
Release : 2007-06-18
Category : Science
ISBN : 9780199719730

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Reaction Mechanisms of Inorganic and Organometallic Systems by Robert B. Jordan Pdf

This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.

Author : Bozzano G Luisa
Publisher : Elsevier
Page : 395 pages
File Size : 40,8 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444597328

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Stereochemistry of Organometallic and Inorganic Compounds by Bozzano G Luisa Pdf

The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies.In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.

Author : Ivan Bernal
Publisher : Unknown
Page : 128 pages
File Size : 50,9 Mb
Release : 1986
Category : Electronic
ISBN : 0444426051

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Stereochemistry of Organometallic and Inorganic Compounds by Ivan Bernal Pdf

Author : D. L. Kepert
Publisher : Springer Science & Business Media
Page : 239 pages
File Size : 41,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642680465

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Inorganic Stereochemistry by D. L. Kepert Pdf

Molecular stereochemistry is a fundamental aspect of all areas of chemistry. It is especially important in inorganic chemistry where the coordination numbers are variable and occasionally quite high. The present book evolved naturally from a series of articles written by Professor Kepert for Progre88 in Inorganic Ohemi8try, elucida ting aspects of the stereochemistry of inorganic compounds of co ordination numbers 4-12. In the present volume, Professor Kepert has added new sections and synthesized these individual chapters into a unified treatment, updating his references when necessary to the most recent contributions in the literature, and inter weaving the various themes as deemed appropriate. The result is a major contribution, describing the stereochemistry of coordi nation compounds having both unidentate and multidentate ligands. The viability of the repulsion approach to stereochemistry is tested to the limit in this treatise and shown to be an extremely good way of rationalizing a diverse body of data.

Author : Norman L. Allinger,Ernest L. Eliel
Publisher : John Wiley & Sons
Page : 504 pages
File Size : 49,7 Mb
Release : 2009-09-17
Category : Science
ISBN : 9780470147443

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Topics in Stereochemistry by Norman L. Allinger,Ernest L. Eliel Pdf

This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.

Author : Alexander von Zelewsky
Publisher : John Wiley & Sons
Page : 272 pages
File Size : 51,8 Mb
Release : 1996-06-03
Category : Science
ISBN : 047195599X

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Stereochemistry of Coordination Compounds by Alexander von Zelewsky Pdf

This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.

Author : P. Zanello
Publisher : Newnes
Page : 678 pages
File Size : 55,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444597052

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Chains, Clusters, Inclusion Compounds, Paramagnetic Labels, and Organic Rings by P. Zanello Pdf

The role of stereochemistry to elucidate reaction patterns and physico-chemical properties in topical subjects ranging from inorganic to organic chemistry are treated in the fifth and final volume of this series. Detailed accounts are given to study: chaining in polyphosphates, electron-transfers in carbonyl clusters, inclusion of organometallic molecules in cyclodextrins, stereochemistry of paramagnetic metal complexes by labeling with nitroxyl radicals, stereocontrol in organic syntheses assisted by inorganic complexes.

Author : Narayan S. Hosmane
Publisher : Academic Press
Page : 276 pages
File Size : 54,5 Mb
Release : 2017-04-27
Category : Science
ISBN : 9780128019931

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Advanced Inorganic Chemistry by Narayan S. Hosmane Pdf

Advanced Inorganic Chemistry: Applications in Everyday Life connects key topics on the subject with actual experiences in nature and everyday life. Differing from other foundational texts with this emphasis on applications and examples, the text uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes. From this foundation, the text explores more advanced topics, such as: Ligands and Ligand Substitution Processes with an emphasis on Square-Planar Substitution and Octahedral Substitution Reactions in Inorganic Chemistry and Transition Metal Complexes, with a particular focus on Crystal-Field and Ligand-Field Theories, Electronic States and Spectra and Organometallic, Bioinorganic Compounds, including Carboranes and Metallacarboranes and their applications in Catalysis, Medicine and Pollution Control. Throughout the book, illustrative examples bring inorganic chemistry to life. For instance, biochemists and students will be interested in how coordination chemistry between the transition metals and the ligands has a direct correlation with cyanide or carbon monoxide poisoning (strong-field Cyanide or CO ligand versus weak-field Oxygen molecule). Engaging discussion of key concepts with examples from the real world Valuable coverage from the foundations of chemical bonds and stereochemistry to advanced topics, such as organometallic, bioinorganic, carboranes and environmental chemistry Uniquely begins with a focus on the shapes (geometry) dictating intermolecular forces of attractions, leading to reactivity between molecules of different shapes

Author : Michael North
Publisher : Routledge
Page : 262 pages
File Size : 40,6 Mb
Release : 2017-10-19
Category : Medical
ISBN : 9781351422062

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Principles and Applications of Stereochemistry by Michael North Pdf

A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.

Author : David L. Kepert
Publisher : Springer Verlag
Page : 0 pages
File Size : 46,6 Mb
Release : 1982
Category : Science
ISBN : 0387107169

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Inorganic Stereochemistry by David L. Kepert Pdf

Author : Michael North
Publisher : Routledge
Page : 269 pages
File Size : 51,6 Mb
Release : 2017-10-19
Category : Medical
ISBN : 9781351422055

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Principles and Applications of Stereochemistry by Michael North Pdf

A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.

Author : J. E. Fergusson
Publisher : Prentice Hall
Page : 330 pages
File Size : 49,8 Mb
Release : 1974
Category : Chemical bonds
ISBN : UCAL:B4477735

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Stereochemistry and Bonding in Inorganic Chemistry by J. E. Fergusson Pdf

A chronicle of Jamestown, the first English colony to survive in the wilderness of the New World.

Author : Marianne Drößmar-Wolf
Publisher : Springer Science & Business Media
Page : 378 pages
File Size : 47,5 Mb
Release : 2013-06-29
Category : Science
ISBN : 9783662071946

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Fe Organoiron Compounds by Marianne Drößmar-Wolf Pdf

"Organoiron Compounds" A, Ferrocene 10 systematicalty covers the literature through the end of 1986 and includes so me references published more recently. A formula index provides ready access to the compounds covered. This volume ends the description of mononuclear unbridged disubstituted ferrocenes, 1 2 FeC HRR . The description of the unbridged disubstituted ferrocenes was initiated with lO a 1 2 "Organoiron Compounds" A, Ferrocene 7 (starting with R and R containing C and Hand 1 containing halogen at least in R\ and continuing with compounds containing 0 at least in R to form alcohols and phenols, their esters, ethers, acetals, and aldehydes), and was foltowed 1 by "Organoiron Compounds" A, Ferrocene 8 (with at least R containing 0). "Organoiron 1 Compounds" A, Ferrocene 9 treated compounds in wh ich at least R contains N, S, Se, B, or Si. This volume now comprises the rest of the disubstituted ferrocenes containing P, As, or a 1 metal at least in R . Beyond that it includes the description of alt the mononuclear unbridged trisubstituted ferrocenes, FeClOH7R1R2R3. Series A so far comprises volumes A 1 to A 10 and has been surveyed in the preface to A 7 (1980). The data in tables are given in abbreviated form without dimensions; for dimensions, explanations, and further abbreviations used, see p. X (next page). Additional remarks are given in the headings of the tables where necessary.