Electrolytes Interfaces And Interphases

Author : Kang Xu
Publisher : Royal Society of Chemistry
Page : 841 pages
File Size : 52,5 Mb
Release : 2023-04-12
Category : Science
ISBN : 9781839166174

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Electrolytes, Interfaces and Interphases by Kang Xu Pdf

Electrolytes are indispensable components in electrochemistry and the fast-growing electrochemical energy storage markets. Research in electrolytes has witnessed exponential growth in recent years, accompanied by their applications in the most popular electrochemical cell ever invented, lithium-ion batteries (LIBs). In myriads of LIBs, electrolytes and their interphases determine how high the voltage of a battery is, how many times it can be charged/discharged, or how rapid the energy stored therein could be released. The conquest of further technical challenges around safety, life and cost-effectiveness of lithium-based or beyond-lithium batteries requires in-depth understanding of electrolytes and interphases. This will be the authoritative textbook for those entering the field. Chapters will establish the fundamental principles for the field, before moving onto important knowledge acquired in recent years. There will be special emphasis on linking these fundamentals to real-world problems encountered in devices, especially lithium-ion batteries. The book will be suitable for advanced undergraduate and postgraduate students in electrochemical energy storage, electrochemistry, materials science and engineering, as well as researchers new to the subject.

Author : Kang Xu
Publisher : Royal Society of Chemistry
Page : 841 pages
File Size : 52,6 Mb
Release : 2023-04-12
Category : Science
ISBN : 9781839163104

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Electrolytes, Interfaces and Interphases by Kang Xu Pdf

The authoritative textbook for those who want to enter the field of electrochemical energy storage research.

Author : Perla B. Balbuena,Yixuan Wang
Publisher : World Scientific
Page : 424 pages
File Size : 52,8 Mb
Release : 2004
Category : Science
ISBN : 9781860943621

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Lithium-ion Batteries by Perla B. Balbuena,Yixuan Wang Pdf

This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.

Author : Jianmin Ma
Publisher : John Wiley & Sons
Page : 299 pages
File Size : 52,5 Mb
Release : 2022-02-09
Category : Science
ISBN : 9783527836383

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Liquid Electrolyte Chemistry for Lithium Metal Batteries by Jianmin Ma Pdf

Liquid Electrolyte Chemistry for Lithium Metal Batteries An of-the-moment treatment of liquid electrolytes used in lithium metal batteries Considered by many as the most-promising next-generation batteries, lithium metal batteries have grown in popularity due to their low potential and high capacity. Crucial to the development of this technology, electrolytes can provide efficient electrode electrolyte interfaces, assuring the interconversion of chemical and electrical energy. The quality of electrode electrolyte interphase, in turn, directly governs the performance of batteries. In Liquid Electrolyte Chemistry, provides a comprehensive look at the current understanding and status of research regarding liquid electrolytes for lithium metal batteries. Offering an introduction to lithium-based batteries from development history to their working mechanisms, the book further offers a glimpse at modification strategies of anode electrolyte interphases and cathode electrolytic interphases. More, by discussing the high-voltage electrolytes from their solvents—organic solvents and ionic liquids—to electrolyte additives, the text provides a thorough understanding on liquid electrolyte chemistry in the remit of lithium metal batteries. Liquid Electrolyte Chemistry for Lithium Metal Batteries readers will also find: A unique focus that reviews the development of liquid electrolytes for lithium metal batteries State-of-the-art progress and development of electrolytes for lithium metal batteries Consideration of safety, focusing the design principles of flame retardant and non-flammable electrolytes Principles and progress on low temperature and high temperature electrolytes Liquid Electrolyte Chemistry for Lithium Metal Batteries is a useful reference for electrochemists, solid state chemists, inorganic chemists, physical chemists, surface chemists, materials scientists, and the libraries that supply them.

Author : Snehashis Choudhury
Publisher : Springer Nature
Page : 230 pages
File Size : 45,7 Mb
Release : 2019-09-25
Category : Technology & Engineering
ISBN : 9783030289430

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Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batteries by Snehashis Choudhury Pdf

This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. This discovery is significant because it overturns a longstanding perception in the field of nanoparticle-polymer hybrid electrolytes that only solid electrolytes with mechanical modulus higher than that of the metal electrode are able to stabilize electrodeposition of reactive metals.

Author : T. Richard Jow,Kang Xu,Oleg Borodin,Makoto Ue
Publisher : Springer
Page : 488 pages
File Size : 51,8 Mb
Release : 2014-05-06
Category : Technology & Engineering
ISBN : 9781493903023

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Electrolytes for Lithium and Lithium-Ion Batteries by T. Richard Jow,Kang Xu,Oleg Borodin,Makoto Ue Pdf

Electrolytes for Lithium and Lithium-ion Batteries provides a comprehensive overview of the scientific understanding and technological development of electrolyte materials in the last several years. This book covers key electrolytes such as LiPF6 salt in mixed-carbonate solvents with additives for the state-of-the-art Li-ion batteries as well as new electrolyte materials developed recently that lay the foundation for future advances. This book also reviews the characterization of electrolyte materials for their transport properties, structures, phase relationships, stabilities, and impurities. The book discusses in-depth the electrode-electrolyte interactions and interphasial chemistries that are key for the successful use of the electrolyte in practical devices. The Quantum Mechanical and Molecular Dynamical calculations that has proved to be so powerful in understanding and predicating behavior and properties of materials is also reviewed in this book. Electrolytes for Lithium and Lithium-ion Batteries is ideal for electrochemists, engineers, researchers interested in energy science and technology, material scientists, and physicists working on energy.

Author : Cai Shen
Publisher : CRC Press
Page : 533 pages
File Size : 54,9 Mb
Release : 2023-05-26
Category : Science
ISBN : 9781000867640

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Microscopy and Microanalysis for Lithium-Ion Batteries by Cai Shen Pdf

The past three decades have witnessed the great success of lithium-ion batteries, especially in the areas of 3C products, electrical vehicles, and smart grid applications. However, further optimization of the energy/power density, coulombic efficiency, cycle life, charge speed, and environmental adaptability are still needed. To address these issues, a thorough understanding of the reaction inside a battery or dynamic evolution of each component is required. Microscopy and Microanalysis for Lithium-Ion Batteries discusses advanced analytical techniques that offer the capability of resolving the structure and chemistry at an atomic resolution to further drive lithium-ion battery research and development. • Provides comprehensive techniques that probe the fundamentals of Li-ion batteries. • Covers the basic principles of the techniques involved as well as its application in battery research. • Describes details of experimental setups and procedure for successful experiments. This reference is aimed at researchers, engineers, and scientists studying lithium-ion batteries including chemical, materials, and electrical engineers, as well as chemists and physicists.

Author : Snehashis Choudhury
Publisher : Unknown
Page : 239 pages
File Size : 52,6 Mb
Release : 2019
Category : Lithium cells
ISBN : 3030289443

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Rational Design of Nanostructured Polymer Electrolytes and Solid-liquid Interphases for Lithium Batteries by Snehashis Choudhury Pdf

This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. This discovery is significant because it overturns a longstanding perception in the field of nanoparticle-polymer hybrid electrolytes that only solid electrolytes with mechanical modulus higher than that of the metal electrode are able to stabilize electrodeposition of reactive metals.

Author : Electrochemical Society. Corrosion Division
Publisher : The Electrochemical Society
Page : 362 pages
File Size : 43,6 Mb
Release : 1993
Category : Science
ISBN : 1566770521

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Proceedings of the Symposium on Microscopic Models of Electrode- Electrolyte Interfaces by Electrochemical Society. Corrosion Division Pdf

Author : René Hausbrand
Publisher : Springer Nature
Page : 109 pages
File Size : 47,9 Mb
Release : 2020-07-20
Category : Science
ISBN : 9783030528263

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Surface Science of Intercalation Materials and Solid Electrolytes by René Hausbrand Pdf

This book shares essential insights into the formation and properties of ionic interfaces based on the energy level structures of their interfaces obtained using a surface science approach. It covers both interfaces with liquid and solid electrolyte contacts, and includes different material classes, such as oxides and phosphates. The specific material properties result in particular effects observed at interfaces, which are often not yet, or not sufficiently, taken into account in battery development and technologies. Discussing fundamental issues concerning the properties of intercalation electrodes and electrode–solid electrolyte interfaces, the book investigates the factors that determine voltage, kinetics and reactivity. It presents experimental results on interface formation, and relates them to electron and ion energy levels in the materials and at their interfaces. It explores these topics integrating electrochemistry, solid-state ionics and semiconductor physics, and accordingly will appeal not only to battery scientists, but also to a broader scientific community, including material scientists and electrochemists.

Author : B. Lucht,T. Jow,R. Bugga,M. Smart,W. Henderson
Publisher : The Electrochemical Society
Page : 25 pages
File Size : 42,5 Mb
Release : 2015-04-30
Category : Science
ISBN : 9781607686040

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Nonaqueous Electrolytes by B. Lucht,T. Jow,R. Bugga,M. Smart,W. Henderson Pdf

Author : Joseph Woicik
Publisher : Springer
Page : 571 pages
File Size : 42,6 Mb
Release : 2015-12-26
Category : Science
ISBN : 9783319240435

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Hard X-ray Photoelectron Spectroscopy (HAXPES) by Joseph Woicik Pdf

This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.

Author : Nithyadharseni Palaniyandy,K. P. Abhilash,B. Nalini
Publisher : Springer Nature
Page : 298 pages
File Size : 44,8 Mb
Release : 2022-11-01
Category : Technology & Engineering
ISBN : 9783031124709

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Solid State Batteries by Nithyadharseni Palaniyandy,K. P. Abhilash,B. Nalini Pdf

This book offers a comprehensive analysis of novel design strategies in higher energy solid-state lithium batteries. It describes synthesis and experimental techniques to characterize the physical, chemical and electrochemical properties of the electrode and electrolytes. The book reports on electrochemical measurements of conductivity and related parameters in solid electrolytes and its interfaces. It also presents various technologies that have been used for the fabrication of all-solid-state lithium-ion batteries such as thin-film, 3D printing (additive manufacturing) and atomic layer deposition. A large part of the text focus on the description on the complete functioning and challenges with the electrochemistry of the electrodes and solid electrolyte interfaces. The book also supplies valuable insight into potential growth opportunities in this exciting market and cost-effective design tactics in solid-state assemblies.

Author : Wladyslaw Wieczorek
Publisher : Jenny Stanford Publishing
Page : 344 pages
File Size : 42,6 Mb
Release : 2021-06-24
Category : Electric batteries
ISBN : 9814877166

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Designing Electrolytes for Lithium-ion and Post-lithium Batteries by Wladyslaw Wieczorek Pdf

Every electrochemical source of electric current is composed of two electrodes with an electrolyte in between. Since storage capacity depends predominantly on the composition and design of the electrodes, most research and development efforts have been focused on them. Considerably less attention has been paid to the electrolyte, a battery's basic component. This book fills this gap and shines more light on the role of electrolytes in modern batteries. Today, limitations in lithium-ion batteries result from non-optimal properties of commercial electrolytes as well as scientific and engineering challenges related to novel electrolytes for improved lithium-ion as well as future post-lithium batteries.

Author : W. Wieczorek,P. Johansson,M. Marcinek,B. Lucht,V. Di Noto
Publisher : The Electrochemical Society
Page : 97 pages
File Size : 52,5 Mb
Release : 2017
Category : Electrolytes
ISBN : 9781607688044

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Battery Electrolytes by W. Wieczorek,P. Johansson,M. Marcinek,B. Lucht,V. Di Noto Pdf